Abstract
The development of storage rings and electromagnetic traps for heavy charged particles is opening up new regimes of atomic physics, including, in particular, spectroscopic studies of Rydberg helium-like ions — with nuclear chargeZ, one electron in the 1s state, and one electron in a near-hydrogenic state of highn andl <n, withn andl the principal and orbital quantum numbers, respectively. We consider the possibility of detecting energy shifts due to retardation, ΔE ret (n,l), Casimir-like effects. These are quantum electrodynamic (QED) retardation effects associated with the finite speed of light. (As opposed to basically kinematic and dynamic QED effects for small quantum numbersn andl, the appropriate expansion parameter forn andl large for retardation QED corrections is notZ(e 2/ħc) but [(Z − 1)/n 2 Z 2](ħc/e 2).) We wish to provide some orientation to those planning experiments in the area, with regard to the choices ofn,l, andZ most likely to be able to generate a high-precision confirmation of a retarded interaction. To do so, we provide extensive tables of estimates, for 1s,nl states, of ΔE ret(n,l), of radiative widths, and ofE, the spin-independent (“electric” fine structure) energy in the absence of retardation shifts, for (nuclear spin zero) ions withZ=2, 6, 8, 16 and 20. These ions might be experimentally accessible in storage rings, and theZ's are low enough that virtual pair production effects may not yet be significant. There is also a brief survey of possible experimental techniques.
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Babb, J.F., Habs, D., Spruch, L. et al. Retardation (Casimir) energy shifts for Rydberg helium-like low-Z ions. Z Phys D - Atoms, Molecules and Clusters 23, 197–209 (1992). https://doi.org/10.1007/BF01437395
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DOI: https://doi.org/10.1007/BF01437395