Abstract
A carborane-containing stable simple enol — 1-2-isopropyl-o-carboran-I-yl)-1-phenyl2-mesityl-2-lrydroxyctlrylcne — has been synthesized. This enol does not isomerize to the starting ketone or keto-enol mixture even after prolonged heating in benzene in the presence of CF3COOH.
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References
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1561–1563, June, 1996.
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Zakharkin, L.I., Ol'shevskaya, V.A. & Zhigareva, G.G. Synthesis of the first stable carborane containing simple enol. Russ Chem Bull 45, 1490–1491 (1996). https://doi.org/10.1007/BF01434241
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DOI: https://doi.org/10.1007/BF01434241