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Analysis of chiroptical properties of π-allyl complex [Pd(β-pinenyl)Cl]2

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Abstract

Electronic absorption and circular dichroism spectra of the optically active [Pd(β-pincnyl)Cl]2 complex (1) have been studied. The assignment of the bands in the circular dichroism spectrum in the d—d-transition region of complex1 was made within the framework of the one-electron model of optical activity; this assignment is in agreement with the literature data on the analysis of the absorption spectrum of (Pd(allyl)Cl]2. The (1R,2S,3S,5R) absolute configuration was suggested for the optical (+)589-isomer of1 studied.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    A. P. Klyagina, T. V. Misailova, I. F. Golovaneva & S. P. Gubin

Authors
  1. A. P. Klyagina
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  2. T. V. Misailova
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  3. I. F. Golovaneva
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  4. S. P. Gubin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1559–1561, June, 1996.

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Klyagina, A.P., Misailova, T.V., Golovaneva, I.F. et al. Analysis of chiroptical properties of π-allyl complex [Pd(β-pinenyl)Cl]2 . Russ Chem Bull 45, 1487–1489 (1996). https://doi.org/10.1007/BF01434240

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  • DOI: https://doi.org/10.1007/BF01434240

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