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Formation of radicals during dimethyldioxirane decomposition

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Abstract

Thermal decomposition of dimethyldioxirane is followed by the formation of radicals registered by ESR spectroscopy using aC-phenyl-N-tert-butylnitronc spin trap. The intensity of the ESR signal increases linearly with increasing temperature; the dependence is extreme in character.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1552–1554, June, 1996.

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Kabal'nova, N.N., Kazakov, D.V., Shishlov, N.M. et al. Formation of radicals during dimethyldioxirane decomposition. Russ Chem Bull 45, 1481–1483 (1996). https://doi.org/10.1007/BF01434237

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  • DOI: https://doi.org/10.1007/BF01434237

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