Abstract
Linear and cyclic permethyloligosilanes were prepared by the Wurtz-type cocondensation of chlorotrimethylsilane and dichlorodimethylsilane in the presence of sodium metal or samarium iodide as reducing agents. The yields and composition of the reaction products depend on the cocondensation conditions.
Similar content being viewed by others
References
G. R. Wilson and A. G. Smith,J. Org. Chem.,1961,26, 557.
M. Kumada and M. Ishikawa,J. Organomet. Chem., 1963,1, 153. 3. M. Kumada, M. Ishikawa, and S. Maeda, J. Organomet. Chem., 1966, 5, 120.
W. G. Boberski and A. L. Allred,J. Organomet. Chem., 1974,71, C27.
R. West,J. Organomet. Chem., 1986,300, 327.
B. G. Zavin, A. I. Chernyavskii, Ya. S. Vygodskii, and N. E. Brandukova,Dokl. Akad. Nauk, 1994,336, 365 [Dokl. Chem., 1994,336, 97 (Engl. Transl.)].
K. Matsumura, L. F. Brough, and R. West,J. Chem. Soc., Chem. Comm., 1978, 1092.
L. F. Brough and R. West,J. Am. Chem. Soc., 1981,103, 3049,
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1520–1522, June, 1996.
Rights and permissions
About this article
Cite this article
Petukhova, O.A., Chernyavskii, A.I., Zavin, B.G. et al. The reductive cocondensation of chlorotrimethylsilane and dichlorodimethylsilane. Russ Chem Bull 45, 1449–1451 (1996). https://doi.org/10.1007/BF01434231
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01434231