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The reductive cocondensation of chlorotrimethylsilane and dichlorodimethylsilane

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Linear and cyclic permethyloligosilanes were prepared by the Wurtz-type cocondensation of chlorotrimethylsilane and dichlorodimethylsilane in the presence of sodium metal or samarium iodide as reducing agents. The yields and composition of the reaction products depend on the cocondensation conditions.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1520–1522, June, 1996.

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Petukhova, O.A., Chernyavskii, A.I., Zavin, B.G. et al. The reductive cocondensation of chlorotrimethylsilane and dichlorodimethylsilane. Russ Chem Bull 45, 1449–1451 (1996). https://doi.org/10.1007/BF01434231

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  • DOI: https://doi.org/10.1007/BF01434231

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