Abstract
Chelate complexes of antimony tetrachloride with dibenzoylmethane and (benzoylchloro-methyl)diphenylphosphine oxide were stndicd by X-ray diffraction, I R, and Raman spectroscopy. The antimony atom has a slightly distorted octahedral coordination in the complexes. The bond lengths in the chelate cycles are evidence for an appreciable electron delocalization in the O-C-C-C-0 and O-C-C-P-0 chains. Unlike the C3O2Sb chelate cycle, the chelate cycle with the phosphorus atom is nonplanar. The assignment of the stretching vibrations frequencies of the C-O, P-0, C-C, Sb-O, and Sb-CI bonds was presumably made on the basis of the IR and Raman spectral data.
Similar content being viewed by others
References
C. Gerard, E. A. C. Lucken, and G. Bernardinelli,J. Chem. Soc. Perkin Trans. 2, 1986, 879.
C. Gerard, C. Dion, and E. A. C. Lucken,J. Chem. Soc. Perkin 2, 1985, 545.
N. Kanchisa, K. Onuma, S. Uda, K. Hirabayashi, Y. Kai, N. Yasuoka, and N. Kasai,Bull. Chem. Soc. Jpn, 1978,51, 2222.
R. R. Holmes, R. O. Day, V. Chandrasexhar, and J. M. Holmes,Inorg. Chem, 1987,26, 157.
M. Brauniger, W. Schwarz, and A. Schmidt,Z. Naturforsch, Ted B, 1979,34, 1703.
K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordinational Compounds, Wiley Interscience Publication, J. Wiley and Sons, Inc., New York, 1986, 301.
H. A. Meinema, A. Mackor, and I. C. Noltes,J. Organomet. Chem., 1972,37, 285.
M. Mikami, I. Nakagawa, and T. Shimanouchi,Spectrochim. Acta, 1967,23A, 1037.
R. E. Hester and R. A. Plane,Inorg. Chem., 1964,3, 513.
L. S. Mayants, E. M. Popov, and M. I. Kabachnik,Opt. i Spectrosc., 1959,7, 170 (in Russian).
L. A. Gribov,Vvedenie v molekulyarnuyu spektroskopiyu [Introduction to Molecular Spectroscopy], Nauka, Moscow, 1976 (in Russian).
A. N. Rodionov,Usp. Khim., 1973,17, 2152 [Russ. Chem. Rev., 1973,17 (Engl. Transi.)].
E. M. Popov and G. A. Kogan,Teor. Eksp. Khim., 1965,1, 295 [Theor. Exp. Chem., 1965,1 (Engl. Transl.)].
D. Brow, I. Hill, and C. E. F. Richard,J. Chem, Soc. A, 1970, 497.
J. P. Clark, W. M. Langford, and C. J. Wilkins.J. Chem. Soc. A, 1967, 792.
S. V. Trepalin and V. P. Novikov,Zh. Prikl. Spectrosc. [J. Appl. Spectrosc.], 1980,33, 545 (in Russian).
Author information
Authors and Affiliations
Additional information
Deceased in 1995.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1474–1479, June, 1996.
Rights and permissions
About this article
Cite this article
Yufit, D.S., Struchkov, Y.T., Garbuzova, I.A. et al. Structural and spectroscopic study of chelate carbonyl and phosphoryl antimony(v) complexes. Russ Chem Bull 45, 1404–1409 (1996). https://doi.org/10.1007/BF01434221
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01434221