Abstract
The formation of mixed CuI and CuII polynuclear complexes with dialkyl sulfide, which are active in the catalytic isomerization of chloroolefins, has been investigated by UV-Vis and ESR spectroscopy. The role of these complexes in catalysis is discussed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1395–1401, June, 1996.
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Rostovshchikova, T.N., Kokorin, A.I., Smirnov, V.V. et al. The structure of catalytically active complexes in copper chloride—dialkyl sulfide—chloroolefin systems. Russ Chem Bull 45, 1325–1331 (1996). https://doi.org/10.1007/BF01434206
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DOI: https://doi.org/10.1007/BF01434206