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Low-temperature hydrodechlorination of 2,3-dichlorodibenzo-p-dioxin and chlorobenzene with hydrides catalyzed by transition metal compounds

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Hydrodechlorination of chlorobcnzene by chemically bound hydrogen in the presence of transition metal compounds was studied. Alkali and alkaline earth metal hydrides (NaH, MgH2, LiAlH4, NaH(LiAlH4)/12) were used as the sources of the chemically bound hydrogen. The effect of the natures of the hydride and of the transition metal on the activity was studied under comparable conditions. The Pd/C-NaH(LiAlH41/2 catalytic system was found to be the most active. This system made it possible to perform the quantitative dechlorination of 2,3-dichlorodibenzo-p-dioxin at 70 °C.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prose. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. I. Simagina, I. V. Stoyanova, V. A. Yakovlev, V. M. Mastikhin & V. A. Likholobov

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. V. Litvak & I. V. Afanasenkova

Authors
  1. V. I. Simagina
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  2. V. V. Litvak
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  3. I. V. Stoyanova
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  4. V. A. Yakovlev
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  5. V. M. Mastikhin
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  6. I. V. Afanasenkova
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  7. V. A. Likholobov
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Additional information

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1391–1394, June, 1996.

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Simagina, V.I., Litvak, V.V., Stoyanova, I.V. et al. Low-temperature hydrodechlorination of 2,3-dichlorodibenzo-p-dioxin and chlorobenzene with hydrides catalyzed by transition metal compounds. Russ Chem Bull 45, 1321–1324 (1996). https://doi.org/10.1007/BF01434205

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  • DOI: https://doi.org/10.1007/BF01434205

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