Abstract
The conversions of cyclohexene and 1,3- and 1,4-cyclohexadiencs treated with neodymium metal under the conditions of mechanochemical activation at 20 °C have been studied. A complicated cycle of conversions, including isomerization, disproportionation, and polymerization, occurs under the reaction conditions. A mechanism for the conversion of the hydrocarbons involving organornetallic intermediates is proposed.
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The conversion of hexane under the conditions used for the reactions with cyclohexene and cyclohexadienes varies only slightly, which makes it possible to use hexane as the internal standard.
Deceased.
Translated fromlzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1386–1390, June, 1996.
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Dolgoplosk, B.A., Vakovlev, V.A., Tinyakova, E.I. et al. Conversions of hydrocarbons treated with neodymium metal under the conditions of mechanochemical activation at room temperature. Russ Chem Bull 45, 1316–1320 (1996). https://doi.org/10.1007/BF01434204
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DOI: https://doi.org/10.1007/BF01434204