Skip to main content
SpringerLink
Log in

Electrospray mass spectrometric study of homogeneous catalytic system Pd(CF3COO)2-Ph2P(CH2)3PPh2-MeOH/Me2CO-H2O for copolymerization of ethylene and carbon monoxide

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The catalytic system Pd(CF3COO)2-Ph2P(CH2)3PPh2-MeOH/Me2CO was studied by electrospray mass spectrometry. The {[Pd(dPPP)2]2+ [(dppp)2Pd(CF3COO)]+, [(dppp)Pd(CF3COO)]+, and [(dppp)Pd(CF3COO)2Pd(dppp)]2+} cations were found in the system. The addition of H2O to the system resulted in the formation of binuclear bicharged ions [(dppp)Pd(OH)]2 2+ and their associates with water.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. A. Sen and T.-W. Lai,J. Am. Chem. Soc., 1982,104, 3520.

    Google Scholar 

  2. E. G. Chepaikin, A. P. Bezruchenko, G. P. Belov, G. N. Boiko, B. B. Tarasov, and S. E. Tkachenko,Vysokomol. Soedin. Ser. B, 1990,32, 593 [Polym. Sci. USSR, Ser. B, 1990,32 (Engl. Transl.)].

    Google Scholar 

  3. T. Drent, J. A. M. van Brockhoven, and M. J. Doyle,J. Organomet. Chem., 1991,417, 235.

    Google Scholar 

  4. Z. Jiang, G. M. Dahlen, K. Houseknecht, and A. Sen,Macromolecules, 1992,25, 2999.

    Google Scholar 

  5. A. Batistini and G. Consiglio,Organometallics, 1992,11,1766.

    Google Scholar 

  6. G. P. Belov, E. G. Chepaikin, A. P. Bezruchenko, and V. I. Smirnov,Vysokomol. Soedin., 1993,35, 1485 [Polym. Sci., 1993,35 (Engl. Transl.)].

    Google Scholar 

  7. Z. M. Dzhabieva, Yu. M. Shul'ga, and G. P. Belov,Zh. Fiz. Khim., 1995,69, 1580 [Russ. J. Phys. Chem., 1995,69 (Engl. Transl.)].

    Google Scholar 

  8. C. Pisano, G. Consiglio, A. Sironi, and M. Moret,Chem. Commun., 1991, 421.

  9. B. Milani, E. Allessio, G. Mestroni, A. Sommarri, F. Garbassi, E. Zangrando, N. Bresciani-Pahor, and L. Randaccio,J. Chem. Soc., Dalton Trans., 1994,13, 1903.

    Google Scholar 

  10. R. van Asselt, E. E. C. G. Gielens, R. E. Rulke, K. Vriere, and C. J. Elsevier,J. Am. Chem. Soc., 1994,116, 977.

    Google Scholar 

  11. R. Colton, B. D. James, I. D. Potter, and J. C. Traeger,Inorg. Chem., 1993,32, 2626.

    Google Scholar 

  12. P. M. Henry,Palladium Catalyzed Oxidation of Hydrocarbon, D. Reidel Publ.,Boston, 1981, 312 p.

    Google Scholar 

  13. J. A. Davis, F. R. Hartley, and S. G. Murray,J. Chem. Soc., Dalton Trans., 1979, No. 11, 1705.

  14. Inventor's Certificate 1681340 (USSR),Byull. Izobr., 1991, No. 36 (in Russian).

  15. L V. Chernushevich, Ph. D. (Phys.-Mat.) Thesis, Chernogolovka, 1991, 136 (in Russian).

  16. V. D. Makhaev, Yu. M. Shul'ga, Z. M. Dzhabieva, G. P. Belov, I. V. Chernushevich, V. i. Kozlovskii, and A. F. Dodonov, Koord. Khim., 1994, 383 [Sov. J. Coord. Chem., 1994 (Engl. Transl.)].

  17. F. Gorla and L. M. Venanzi,Helv. Chim. Acta 1990,73, 2659.

    Google Scholar 

  18. G. P. Belov, O. N. Golodkov, and Z. M. Dzhabieva,Macromol. Symp.,89, 1995, 455.

    Google Scholar 

  19. A. van der Bergen, R. Colton, M. Percy, and B. O. West,Inorg. Chem., 1993,32, 3408.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, 142432, Moscow Region, Russian Federation

    Z. M. Dzhahieva, Yu. M. Shul'ga & G. P. Belov

  2. Institute of Energy Problems of Chemical Physics 0(Branch), Russian Academy of Sciences, Chernogolovka, 142432, Moscow Region, Russian Federation

    V. P. Kozlovskii & A. F. Dodonov

Authors
  1. Z. M. Dzhahieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Kozlovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. M. Shul'ga
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. F. Dodonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. P. Belov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 494–496, February, 1996

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dzhahieva, Z.M., Kozlovskii, V.P., Shul'ga, Y.M. et al. Electrospray mass spectrometric study of homogeneous catalytic system Pd(CF3COO)2-Ph2P(CH2)3PPh2-MeOH/Me2CO-H2O for copolymerization of ethylene and carbon monoxide. Russ Chem Bull 45, 474–476 (1996). https://doi.org/10.1007/BF01434001

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01434001

Key words

Search

Navigation