Abstract
Diketocarbene generated by rhodium(II) acetate-catalyzed decomposition of diazodimedone reacts with benzene at room temperature to give 5,5-dimetlryl-2-phenylcyclohexane-1,3-dione in 88% yield.
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Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 491–493, February, 1996
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Chapyshev, S.V., Nakano, H. & Ibata, T. Formal C-H insertion of diketocarbene generated by rhodium(II)-catalyzed decomposition of diazodimedone into a benzene molecule. Russ Chem Bull 45, 471–473 (1996). https://doi.org/10.1007/BF01434000
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DOI: https://doi.org/10.1007/BF01434000