Abstract
Mercury(u) dinitramidate Hg(N3O4)2 (MDNA) has been synthesized. Its electronic and vibrational spectra show that in the crystalline state and in solutions in nonpolar solvents, MDNA is a covalent compound, the mercury atom being bound to the oxygen atoms. In polar solvents, MDNA dissociates to give mercury(u) cation and dinitramide anion N3O4 −.
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References
V. A. Shlyapochinikov,Kolebatel'nye spektry alifaticheskikh nitrosoedinenii [Vibrational Spectra of Aliphatic Nitro Compounds], Nauka, Moscow, 1989 (in Russian).
O. A. Luk'yanov, O. V. Anikin, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1546 [Russ. Chem. Bull., 1994,43, 1457 (Engl. Transl.)].
V. A. Shlyapochnikov, G. I. Oleneva, N. O. Cherskaya, O. A. Luk'yanov, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1995, 1508 [Russ. Chem. Bull., 1995,44, 1449 (Engl. Transl.)]
V. A. Shlyapochnikov, N. O. Cherskaya, O. A. Luk'yanov, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1610 [Russ. Chem. Bull., 1994,43, 1522 (Engl. Transl.)].
O. A. Luk'yanov, NA. Shlykova, and V. A. Tartakovsky,Izv, Akad. Nauk, Ser. Khim., 1994, 1775 [Russ. Chem. Bull., 1994,43, 1680 (Engl. Transl.)].
V. G. Avakyan, V. A. Shlyapochnikov, and V. V. Volkova,Izv. Akad. Nauk, Ser. Khim., 1995, 1503 [Russ. Chem. Bull., 1995,44, 1444 (Engl. Transl.)].
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For Communication 7, sec Ref. 3
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 447–450, February, 1996.
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Shlyapochnikov, V.A., Cherskaya, N.O., Luk'yanov, O.A. et al. Dinitramide and its salts. Russ Chem Bull 45, 430–432 (1996). https://doi.org/10.1007/BF01433989
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DOI: https://doi.org/10.1007/BF01433989