Abstract
The reaction of 2,6-dibenzylidenecyclohexanone with PCl5 occursvia the sequential stages of desoxychlorination and substitutional phosphorylation to form (after oxidation, methoxylation, and hydrolysis on the surface of the chromatographic SiO2 adsorbent) organophosphorus products of the 1-(a-chloro-, a-hydroxy-, or α-alkoxy)benzyl-2-chloro-3-(α-(dimethylphosphoryl)benzylidene)cyclobex-1-ene series.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 441–443, February, 1996.
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Nikanorov, V.A., Rogachev, A.D., Galakhov, M.V. et al. Reaction of 2,6-dibenzylidenecyclohexanone with phosphorus pentachloride: Triple functionalization of the isosemiquinoid system. Russ Chem Bull 45, 424–426 (1996). https://doi.org/10.1007/BF01433987
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DOI: https://doi.org/10.1007/BF01433987