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Synthesis and structures of 1-[1-(4-R-benzoyl)-2-ethoxyvinyl]-2-dicyanomethylene-1,2-dihydropyridines

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reaction of (4-R-benzoyl)(2-bromopyridinitim) methylides with ethoxyrnethylene-rnalononitrile is stereoselective and affords Z-1-[1-(4-R-benzoyl)-2-ethoxyvinyl]-2-dicyationietliylene-1,2-dihydropyridines. The structure of 1-[1-(4-chlorobenzoyl)-2 ethoxyvinyll-2-dicyanomethylene-1,2-dihydropyridine has been established by X-ray structural study.

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Authors and Affiliations

  1. East-Ukraine University, 2 ul. Oboronnaya, 348011, Lugansk, Ukraine

    I. A. Aitov & Yu. A. Sharanin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. N. Nesterov & Yu. T. Strachkov

Authors
  1. I. A. Aitov
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  2. V. N. Nesterov
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  3. Yu. A. Sharanin
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  4. Yu. T. Strachkov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 434–436, February, 1996.

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Aitov, I.A., Nesterov, V.N., Sharanin, Y.A. et al. Synthesis and structures of 1-[1-(4-R-benzoyl)-2-ethoxyvinyl]-2-dicyanomethylene-1,2-dihydropyridines. Russ Chem Bull 45, 417–419 (1996). https://doi.org/10.1007/BF01433985

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  • DOI: https://doi.org/10.1007/BF01433985

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