Abstract
The decomposition of 2-chloro-, 2,2-dichloro-, and 2,6-dichloro-substituted cyclohexanone hydroperoxides on treatment with ferrous chloride and sulfate to give chloro-substituted aliphatic acids was investigated. A method for the synthesis of 2,6,6-trichlorohexanoic and 2,6,7,11-tetrachlorododecane-1,12-dioic acids was elaborated.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 143–146, January, 1996.
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Starostin, E.K., Gushchin, V.V., Ignatenko, A.V. et al. Decyclization of chiorocyclohexanone hydroperoxides under the action of ferrous salts. Russ Chem Bull 45, 133–136 (1996). https://doi.org/10.1007/BF01433747
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DOI: https://doi.org/10.1007/BF01433747