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High resolution spectroscopy on 6sns Rydberg states of barium

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Zeitschrift für Physik A Atoms and Nuclei

Abstract

Extensive new data on perturbed and unperturbed levels of the 6s n s 1 S 0 and 6s n s 3 S 1 Rydberg series of Barium have been obtained in a high-resolution laser atomic-beam experiment. Special attention has been paid to the region aboven=15 where the3 S 1 series is strongly perturbed. The results on hyperfine energies and isotopic field shift ratios are compared with calculations using wavefunctions obtained from a Multi Channel Quantum Defect analysis. The applicability of various approximations to these wavefunctions is discussed. Good agreement between experiment and calculation is obtained.

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We would like to express our sincere gratitude to Dr. Aymar and Dr. Camus for sending us a wealth of material in advance of publication. We gratefully acknowledge the Stichting voor Fundamenteel Onderzoek der Materie for partial financial support.

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Hogervorst, W., Eliel, E.R. High resolution spectroscopy on 6sns Rydberg states of barium. Z Physik A 310, 19–26 (1983). https://doi.org/10.1007/BF01433606

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  • DOI: https://doi.org/10.1007/BF01433606

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