Abstract
Differential cross sections have been measured for He(23 S)+Ne at kinetic energies between 28 and 370 meV. For energies above 90meV the elastic cross sections show Stückelberg oscillations from curve crossings, which lead to the energy exchange process: He(23 S)+Ne→He(11 S)+Ne(2p 5 4s,3d,4p). Differential cross sections for this inelastic process could be measured above 200 meV. A fit to the data gives the potentials for He(23 S)+Ne and, less accurately, for He+Ne*. These results offer a simple explanation, why the exothermic pumping process of the infrared lines of the HeNe laser has a threshold of about 80 meV and a small cross section.
Similar content being viewed by others
References
Brutschy, B., Haberland, H.: Phys. Rev. Lett.38, 689 (1977)
Brutschy, B., Haberland, H.: Phys. Rev. A19, 2232 (1979)
Jordan, R.M., Siska, P.E.: J. Chem. Phys.69, 4634 (1978)
Haberland, H., Lee, Y.T., Siska, P.E.: Ad. Chem. Phys.47, 487 (1981)
Rundel, R.D., Stebbings, R.F.: Case Studies in Atomic Collision Physics II. McDaniel, E.W., McDowell, M.R.C. (eds.), p. 549. Amsterdam: North Holland 1972
Hotop, H., Kolb, E., Lorenzen, J.: J. Electron Spectrosc. Relat. Phenom.16, 213 (1979)
Niehaus, A.: Ad. Chem. Phys.47, 399 (1981)
Bennett Jr, W.R.: Appl. Opt (Suppl. on Opt. Mas.), p.24 (1962), or any book on gas lasers
Miller, W.H., Morgner, H.: J. Chem. Phys.67, 4923 (1977)
van Dyck, R.S., Johnson, C.E., Shugart, H.A.: Phys. Rev. A5, 991 (1972)
Benton, E.E., Ferguson, E.E., Matsen, F.A., Robertson, W.W.: Phys. Rev.128, 206 (1962)
White, A.D., Gordon, E.I.: Appl. Phys. Lett.3, 197 (1963)
Massey, J.T., Schulz, A.G., Hochheimer, B.F., Cannon, S.M.: J. Appl. Phys.36, 658 (1965)
Arrathoon, R.: Phys. Rev. A4, 203 (1971)
Arrathoon, R.: Phys. Rev. Lett.30, 469 (1973)
Oesterlin, P., Haberland, H., Schmidt, K.: X. ICPEAC, Paris 1977, book of abstracts, p. 558
Haberland, H., Oesterlin, P.: VII Int. Symp. Mol. Beams, Trento 1979, book of abstracts, p. 78
Siska, P.E., Fukuyama, T.: X. ICPEAC, Paris 1977, book of abstracts p. 552
Fukuyama, T., Siska, P.E.: XI. ICPEAC, Kyoto 1979, book of abstracts, p. 460
Conrad, H., Ertl, G., Küppers, J., Gérard, K., Haberland, H.: Phys. Rev. Lett.42, 1082 (1979)
Conrad, H., Ertl, G., Küppers, J., Sesselmann, W., Haberland, H.: Surf. Sci.100, L461 (1980)
Kubota, H., Hirooka, T., Fukuyama, T., Kondow, T., Kuchitsu, K., Yencha, A.J., J. Electron Spectrosc. Relat. Phenom.23, 417 (1981)
Yencha, A.J., Kubota, H., Fukuyama, T., Kondow, T., Kuchitsu, K., ibid., p. 431
Oesterlin, P.: Thesis, Freiburg 1979 (unpublished)
Schmidt, K.: Thesis, Freiburg 1976 (unpublished)
Haberland, H., Oesterlin, P., Schmidt, K.: J. Chem. Phys.65, 3373 (1976)
Child, M.S., Gerber, R.B.: Mol. Phys.38, 421 (1979)
Langer, R.E.: Phys. Rev.51, 669 (1937)
Berry, M.V., Mount, K.F.: Rep. Progr. Phys.35, 315 (1972)
Smith, F.J.: Physica30, 497 (1964)
Delos, J.B., Thorson, W.R.: Phys. Rev. A6, 728 (1972)
Siska, P.E., Parson, J.M., Schafer, T.P., Lee, Y.T., J. Chem. Phys.55, 5762 (1971)
Bell, K.L., Dalgarno, A., Kingston, A.E.: J. Phys. B1, 18 (1968)
Peach, G.: J. Phys. B11, 2107 (1978)
Siska, P.E.: J. Chem. Phys.71, 3942 (1979)
Siska, P.E.: J. Chem. Phys.73, 2372 (1980)
Condon, E.U., Shortley, G.H.: The Theory of Atomic Spectra. Cambridge: Univ. Press 1977
Racah, G.: Phys. Rev.61, 537 (1942)
Guberman, S.L., Goddard III, W.A.: Phys. Rev. A12, 1203 (1975)
Roemelt, J.: private communication (1979)
Dabrowski, I., Herzberg, G.: J. Mol. Spectrosc.73, 183 (1978)
Hoffmann, V., Morgner, H.: J. Phys. B12, 2857 (1979)
Landau, L.D., Lifshitz, E.M.: Course of theoretical physics III: Quantum mechanics. London: Pergamon Press 1958
Cooper, D. (Oxford): Private communication (1980)
Russek, A.: Phys. Rev. A4, 1918 (1971)
Haberland, H., Oesterlin, P.: (to be published)
Beterov, I.M., Chebotaev, V.P.: Opt. Spectrosc.20, 597 (1966)
Jones, C.R., Robertson, W.W.: Bull. Am. Phys. Soc.13, 198 (1968)
Jones, C.R., Niles, F.E., Robertson, W.W.: J. Appl. Phys.40, 3967 (1969)
Lindinger, W., Schmeltekopf, A.L., Fehsenfeld, F.C.: J. Chem. Phys.61, 2890 (1974)
Young Jr., R.T., Willett, C.S., Maupin, R.T.: J. Appl. Phys.41, 2936 (1970)
Author information
Authors and Affiliations
Additional information
This work was financially supported by the Deutsche Forschungsgemeinschaft. We would like to thank Dr. I. Dabrowski (Ottawa) for sending us the RKR potentials for HeNe+ and Prof. U. Fano (Chicago) for a very illuminating discussion on spin-orbit effects in molecules. Mr. D. Cooper (Oxford) calculated theR-dependence of the spin-orbit matrix element within two days, after learning of this problem.
Rights and permissions
About this article
Cite this article
Haberland, H., Oesterlin, P. Interaction potentials and energy transfer cross sections for collisions of metastable helium and neon I: He(23 S)+Ne. Z Physik A 304, 11–21 (1982). https://doi.org/10.1007/BF01432271
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01432271