Abstract
The crystal structure of the product of the condensation of (salicylideneamino)nitroguanidine with salicylaldehyde on a Ni2+ ion template, K[Ni(C15H10N5O4)] · DMF, has been studied. It was established that a planar Ni complex, consisting of isolated [NiL]− anions and solvated [K+ · DMF] cations, is formed. The negative charge of the anion is localized mainly on the O atoms of the nitro group. The nitroguanidine fragment of the ligand occurs in the tautomeric form, which was not reported previously.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2273–2277, September, 1996.
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Starikova, Z.A., Yanovsky, A.I., Struchkov, Y.T. et al. Molecular structure of potassium [N,N′-bis(salicylideneamino)nitroguanidonate-N,N′,-O,O′]nickel(ii), the product of condensation of (salicylideneamino)nitroguanidine with salicylaldehyde on a Ni2+ ion template. Russ Chem Bull 45, 2157–2162 (1996). https://doi.org/10.1007/BF01430730
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DOI: https://doi.org/10.1007/BF01430730