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Polyferroorganosiloxanes as catalysts of oxidation processes

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Abstract

Polyferroorganosiloxanes were studied as catalysts for homogeneous oxidation of alkanes by hydrogen peroxide tinder mild conditions. In the oxidation of cyclohexane the catalysts are characterized by high efficiency (conversion of hydrogen peroxide is 25%) and stability Kip to 80 cycles per gat NJ The min product of the oxidation W do presence a 2,4,6-tri-tert-btitylphenol is cyclohexanol (tip to 35% per H2O2).

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Authors and Affiliations

  1. Russian Academy of Sciences, Institute of Chemical Physics in Chernogolovka, Chernogolovka, 142432, Moscow Region, Russian Federation

    V. S. Kulikova

  2. Russian Academy of Sciences, N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    M. M. Levitsky

  3. Russian Academy of Sciences, N. N. Semenov Institute of Chemical Physics, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    A. L. Buchachenko

Authors
  1. V. S. Kulikova
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  2. M. M. Levitsky
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  3. A. L. Buchachenko
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Kulikova, V.S., Levitsky, M.M. & Buchachenko, A.L. Polyferroorganosiloxanes as catalysts of oxidation processes. Russ Chem Bull 45, 2870–2872 (1996). https://doi.org/10.1007/BF01430666

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  • DOI: https://doi.org/10.1007/BF01430666

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