Abstract
Interaction of Bu4NB3H8 with AlCl3 at 45–50 °C results in the formation of BH4 − and unstable borane B2H4, which is converted into a mixture of B4H10, B5H9, and B2H6. This reaction can be used for the preparation of tetraborane(10).
This is a preview of subscription content, log in via an institution to check access.
References
L. V. Titov, E. R. Erernin, V. P. Nikol 'skaya, and V. Ya. Rosolovskii,Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 2212 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1978,27, 1953 (Engl. Transl.)]
V. D. Sasnovskaya and L. V. Titov,Izv. Akad. Nauk SSSR, Ser. Khim., 1984, 417 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984,33, 378 (Engl. TransI.)].
M, D. Levicheva, L. V, Titov, and L. V. Zhemchugova,Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 2120 [Bull. Acad. Sci, USSR, Div. Chem. Sci., 1987,36, 1971 (Engl. Transl.)].
I. M. MakhIouf, W. V. Hough, and G. T. Hefferan,Inorg. Chem., 1967,6, 1196.
L. V. Titov, M. D. Levicheva, and V. Ya. Rosolovskii,Zh. Neorg. Khim., 1980,25, 2953 [Russ. J. Inorg. Chem., 1980,25, 2671 (Engl. Transl.)].
L. V. Titov, M. D. Levicheva, and S. B. Psikha,Zh. Neorg. Khim., 1984,29, 668 [Russ. J. Inorg. Chem., 1984,29, 386 (Engl. Transl)].
L. V. Titov, L, A. Gavrilova, L. N. Erofeev, and V. Ya, Rosolovskii,Izv. Akad. Nauk SSSR, Ser. Khim., 1974, 10 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1974,23, 8 (Engl. Transl.)].
D. F. Games and R. Schaeffer,Inorg. Chem., 1964,3, 438.
R. Schaeffer and F. N. Tebbe,J. Am. Chem. Soc., 1962,84, 397?
J. B. Leach, M. A. Toft, F. L. Himpsl, and S. G. Shore,J. Am. Chem. Soc., 1981,103, 988.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Titov, L.V., Zhemchugova, L.V. Interaction of tetrabutylammonium octahydrotriborate with aluminum chloride. A new method for the preparation of tetraborane(10). Russ Chem Bull 45, 2863–2864 (1996). https://doi.org/10.1007/BF01430663
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01430663