Abstract
Some reactions of the adduct of nonaniethylferrocenecarbaldehyde with HBF4, [Me5C5FeC5Me4CH+(OH)]BF4 −, and its transformation into the paramagnetic complex [Me5C5Fe+-C5Me4CH=O]BF4 − were studied. The structure of the complex was established from the chemical properties, the data from IR spectroscopy, mass spectrometry, and1H,13C, and19F NMR spectroscopy and confirmed by independent synthesis.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp, 2979–2983, December, 1996.
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Kruglova, N.V., Rybinskaya, M.I., Kreindlin, A.Z. et al. Adduct of nonamethylferrocenecarbaldehyde with HBF4 and its transformations. Russ Chem Bull 45, 2830–2834 (1996). https://doi.org/10.1007/BF01430654
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DOI: https://doi.org/10.1007/BF01430654