Abstract
A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-metliylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2976–2978, December, 1996,
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Chernyavskaya, N.A., Kurykin, M.A. Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene. Russ Chem Bull 45, 2827–2829 (1996). https://doi.org/10.1007/BF01430653
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DOI: https://doi.org/10.1007/BF01430653