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Interaction of dimethylsulfoxonium methylide with 5-allyl-2,3,5-trichloro-4,4-dimethoxycyclopent-2-en-1-one

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Dimethylsulfoxonium methylide in DMSO initiates unusual oxidative skeletal transformations of trichlorocyclopentenone. Lactone, cyclic orthoester, and a number of by-products of hydrolysis, substitution, and reduction were isolated and characterized. The expected epoxide was obtained in low yield.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    N. A. Ivanova, A. M. Shainurova, I. I. Furlei & M. S. Miftakhov

Authors
  1. N. A. Ivanova
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  2. A. M. Shainurova
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  3. I. I. Furlei
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  4. M. S. Miftakhov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2958–2960, December, 1996.

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Ivanova, N.A., Shainurova, A.M., Furlei, I.I. et al. Interaction of dimethylsulfoxonium methylide with 5-allyl-2,3,5-trichloro-4,4-dimethoxycyclopent-2-en-1-one. Russ Chem Bull 45, 2810–2812 (1996). https://doi.org/10.1007/BF01430648

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  • DOI: https://doi.org/10.1007/BF01430648

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