Skip to main content
Log in

Unexpected condensation of 3-chloro-1,2,3-trimethyl-4-methylidenecyclobutene with 1,2-dimethyl-3,4-dimethylidenecyclobutene

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Condensation of 3-chloro-1,2,3-trimethyl-4-methylidenecyclobutene with 1,2-dimethyl-3,4-dimethylidenecyclobutene under the action of MgBr2 leading to spiro compounds was observed. The scheme of the process is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Criegee, H. Hofmaister, and G. Bolk,Chem. Ber., 1965,98, 2327.

    Google Scholar 

  2. H. Mayr, H. Klein, and G. Kolberg,Chem. Ber., 1984,117, 2555.

    Google Scholar 

  3. R G. Gassman and D. A. Singleton,J. Am, Chem. Soc., 1984,106, 6085; S. A. Osadchii, V, A. Drobysh, M. M. Shakirov, V. I. Mamatyuk, and V. G. Shubin,Zh. Org. Khim., 1988,24, 267 [J. Org. Chem. USSR, 1988,24 (Engl. Transl.)].

    Google Scholar 

  4. F. A. Allen, O. Kennard, D. G. Watson, L, Brammer, A. G. Orpen, and R. Taylor,J. Chem. Soc., Perkin Trans. 2, 1987, S1.

  5. G. B. Bokii,Kristallokhimiya [Crystal Chemistry], Nauka, Moscow, 1971, 138 pp. (in Russian),

    Google Scholar 

  6. A. A. Bliznyuk and A. A. Voityuk,Zh. Strukt. Khim., 1986,27, No. 4, 190 [J. Struct. Chem., 1986,27, No. 4 (Engl. Dana)].

    Google Scholar 

  7. R. Criegee, J. Dekker, W. Engel, R. Ludwig, and K. Noll,Chem. Ber., 1963,96, 2362.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

As far as we know, cation2 was not generated before under <long> life conditions.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2955–2957, December, 1996.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Osadchii, S.A., Kochubei, N.V., Shakirov, M.M. et al. Unexpected condensation of 3-chloro-1,2,3-trimethyl-4-methylidenecyclobutene with 1,2-dimethyl-3,4-dimethylidenecyclobutene. Russ Chem Bull 45, 2807–2809 (1996). https://doi.org/10.1007/BF01430647

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01430647

Key words

Navigation