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Anodic perfluoroalkylation of the enol acetate of ethyl acetoacetate

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Electrochemical perfluoroalkylation of the enol acetate of ethyl acetoacetate was studied in the conditions of the Kolbe reaction. The yields of alkylation products depend on the competing adsorption of the enol acetate, the solvent, and perfluorocarboxylates on the surface of a platinum electrode.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    V. P. Kislyi, N. D. Kagramanov & V. V. Semenov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    M. A. Kurykin

  3. A. N. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071, Moscow, Russian Federation

    V. A. Grinberg

Authors
  1. V. P. Kislyi
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  2. M. A. Kurykin
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  3. V. A. Grinberg
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  4. N. D. Kagramanov
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  5. V. V. Semenov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2948–2951, December, 1996.

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Kislyi, V.P., Kurykin, M.A., Grinberg, V.A. et al. Anodic perfluoroalkylation of the enol acetate of ethyl acetoacetate. Russ Chem Bull 45, 2800–2803 (1996). https://doi.org/10.1007/BF01430645

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  • DOI: https://doi.org/10.1007/BF01430645

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