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Investigation of the reaction of peroxide radicals derived from di-n-butyl ether withp-phenylenediamine by kinetic spectrophotometry

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The kinetics of consumption ofp-phenylenediamine (PDA) in di-n-butyl ether (BE) subjected to oxidation was measured by following the accumulation of the product of the transformation of PDA. The effective rate constant of the reaction of peroxide radicals derived from BE (RO2) with PDA was measured (k 7 = 2·104 L mol−1 s-1) by the inhibitor method, Evidence confirming the formation of a stable complex of RO2, with PDA were obtained. This leads to retardation of oxidation without the formation of hydroperoxides of BE (ROOH) in the acts of chain termination on PDA.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. V. Zolotova & Y. Y. Kharitonov

Authors
  1. N. V. Zolotova
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  2. Y. Y. Kharitonov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No, 12, pp. 2902–2903, December, 1996.

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Zolotova, N.V., Kharitonov, Y.Y. Investigation of the reaction of peroxide radicals derived from di-n-butyl ether withp-phenylenediamine by kinetic spectrophotometry. Russ Chem Bull 45, 2753–2754 (1996). https://doi.org/10.1007/BF01430636

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  • DOI: https://doi.org/10.1007/BF01430636

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