Abstract
Based on the data for the initial stage of aging of metal hydroxides that exhibit nitrogen fixation properties and the exact solution of the model kinetic problem for the association of aqua and hydroxo complexes, the regularities of the formation of the structure of primary amorphous particles of metal hydroxides have been revealed. The primary particles consist of chain hydroxo polymers that containca. 10 units and are chemically bound to each other by μ3-OH bridging groups in sites at chaotically arranged intersections.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya. No. 12, pp. 2852–2857, December, 1996. 1996.
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Denisov, N.T., Shestakov, A.F. Initial stages of the formation of the structure of metal hydroxides. Russ Chem Bull 45, 2703–2708 (1996). https://doi.org/10.1007/BF01430626
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DOI: https://doi.org/10.1007/BF01430626