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Hindered rotation around\(C\dddot ---N\) bond in π-complexes of 6-dimethylaminofulvene with group VIB metal carbonyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An increase in the barriers of rotation around the\(C\dddot ---N\) bond is observed when dimethylaminofulvene is coordinated with transition metal (Cr, Mo, W) carbonyls.

  2. 2.

    In weakly acid media, where the complexes are protonated at the N atom, the barrier of rotation decreases, while in strongly acid media, where the metal atom is protonated, it increases.

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Literature cited

  1. H. Kessler, Tetrahedron,30, No. 13, 1861 (1974).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. I. Bakhmutov, B. N. Strunin & V. N. Setkina

Authors
  1. V. I. Bakhmutov
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  2. B. N. Strunin
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  3. V. N. Setkina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1652–1653, July, 1981.

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Bakhmutov, V.I., Strunin, B.N. & Setkina, V.N. Hindered rotation around\(C\dddot ---N\) bond in π-complexes of 6-dimethylaminofulvene with group VIB metal carbonyls. Russ Chem Bull 30, 1341–1342 (1981). https://doi.org/10.1007/BF01418011

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  • DOI: https://doi.org/10.1007/BF01418011

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