Abstract
A creep study has been made of 2% pectin gels in the 1∶1 water-glycerol mixture in the temperature interval 284.7 to 321.7 °K, and also of water-glycerol pectin gels concentrated to 2–5% at 290.7 °K. Water-glycerol pectin gels by their thermorheological properties are close to water-sucrose gels studied earlier. It is shown that the rate of the relaxation processes is independent of the concentration. The standard break-down enthalpy of the 2% gel cross-links in the temperature interval where rheological properties are measured, is 17–39 kJ · mole−1.
Similar content being viewed by others
References
Plashchina, I. G., O. A. Fomina, E. E. Braudo, V. B. Tolstoguzov, Coll. Polym. Sci.257, 1180 (1979).
Plashchina, I. G., M. G. Semyenova, E. E. Braudo, V. B. Tolstoguzov, Carbohydrate Polym., in press (1983).
Berth, G., H. Anger, I. G. Plashchina, E. E. Braudo, V. B. Tolstoguzov, Ibid.2, 1 (1982).
Yuryev, V. P., E. E. Braudo, V. B. Tolstoguzov, Coll. Polym. Sci.261, 210 (1983).
Braudo, E. E., D. B. Isjumow, V. B. Tolstoguzov, E. S. Wainerman, Nahrung18, 1 (1974).
Ferry J. D., Viscoelastic Properties of Polymers, 2nd ed., J. Wiley & Sons, Inc. New York-London-Sydney-Toronto (1970).
Braudo, E. E., D. B. Isjumow, V. B. Tolstoguzov, Nahrung17, 773 (1973).
Hirai, N., Bull. Inst. Chem. Res. Kyoto Univ.33, 21 (1955).
Bikbov, T. M., V. Ya. Grinberg, H. Shmandke, T. S. Chaika, I. A. Vaintraub, V. B. Tolstoguzov, Coll. Polym. Sci.259, 536 (1981).
Bartenev, G. M., Structure and Relaxation Properties of Elastomers, Khimiya Publishers, Moscow, p. 73 (1979).
Bartenev, G. M., Proc. Kuban Univ.242, 7 (1977).
Frenkel, Ya. I., The Kinetic Theory of Liquids, Akad. Nauk SSSR Publishers, Moscow-Leningrad, p. 393 (1945).
Eldridge, J. E., J. D. Ferry, J. Phys. Chem.58, 992 (1954).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Plashchina, I.G., Gotlieb, A.M., Braudo, E.E. et al. Creep study of high-esterified pectin gels. Colloid & Polymer Sci 261, 672–676 (1983). https://doi.org/10.1007/BF01415039
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01415039