Skip to main content
SpringerLink
Log in

Polyvinylpyridine with oleic acid and polymethylmethacrylate mixtures in monolayers

  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Studies were carried out on mixed monolayers of a polymer with ionizable polar groups and a practically “horizontal” disposition, poly-2-vinylpyridine, with i) a low-molecular-weight substance likewise with a horizontal disposition, oleic acid, and ii) a non-ionic polymer, again with a horizontal disposition of the hydrocarbon chains, polymethyl-methacrylate.

The mutual compatibility of the components in all mole ratios, and the greater thermodynamic stability of the mixtures, were shown in both systems.

A comparison of the spreading isotherms at the W/air, W/hexane, W/octane, w/benzene and W/1,2-dichlorobenzene interfaces suggests that the mutual miscibility is attributable to interactions among the chains and among the polar groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Gabrielli, G., M. Puggelli, E. Ferroni, J. Coll. Interface Sci.47, 145 (1974); M. Pugelli, G. Gabrielli, J. Coll. Interface Sci.61, 420 (1977); G. Gabrielli, P. Baglioni, J. Coll. Interface Sci.73, 582 (1980); G. Gabrielli, M. Puggelli, P. Baglioni, J. Coll. Interface Sci.86, 485 (1982).

    Google Scholar 

  2. Gabrielli G., J. Coll. Interface Sci.53, 148 (1975); G. Gabrielli, A. Maddii, J. Coll. Interface Sci.64, 19 (1978); G. Gabrielli, P. Baglioni, A. Maddii, J. Coll. Interface Sci.79, 268 (1981).

    Google Scholar 

  3. Puggelli, M., G. Gabrielli, Colloid Polymer Sci.261, 82 (1983).

    Google Scholar 

  4. Puggelli, M., G. Gabrielli, Colloid Poylmer Sci.261, 166 (1983).

    Google Scholar 

  5. Davies, J. T., E. K. Rideal, Interfacial Phenomena, p. 265, Academic Press, N. Y. (1963).

    Google Scholar 

  6. Gabrielli, G., P. Baglioni, E. Ferroni, Colloid Polymer Sci.257, 1207 (1979).

    Google Scholar 

  7. Ries, H. E., Jr., D. C. Walker, J. Coll. Interface Sci.16, 361 (1961); H. E. Ries, Jr., N. Beredjick, “Proceedings of IVth International Congress Surface Active Subst.” — Bruxelles (1964); G. L. Gaines, Jr., “Insoluble Monolayers at Liquid-Gas Interfaces”, pp. 163–164, Interscience Publ., New York (1966); J. R. Miller, J. Colloid Sci. Supl.,1, 9 579 (1954).

    Google Scholar 

  8. Gabrielli, G., G. Guarini, — J. Coll. Interface Sci.64, 185 (1978).

    Google Scholar 

  9. Bacon, K. J., G. T. Barnes, — J. Coll. Interface Sci.67, 70 (1978).

    Google Scholar 

  10. Polymer Handbook — Ed. Brandrup-Immergut, E. H. — Wiley Publ. — N.Y. Sec. Ed. 1975.

Download references

Author information

Author notes

  1. Gabriella Gabrielli

    Present address: Institute of Physical Chemistry University of Florence, Florence, Italy

Authors and Affiliations

  1. Institute of Physical Chemistry University of Florence, Florence, Italy

    Marta Puggelli

Authors
  1. Marta Puggelli
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Gabriella Gabrielli
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This paper was sponsored by C. N. R., “Progetto finalizzato Chimica fine e secondaria”.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Puggelli, M., Gabrielli, G. Polyvinylpyridine with oleic acid and polymethylmethacrylate mixtures in monolayers. Colloid & Polymer Sci 261, 667–671 (1983). https://doi.org/10.1007/BF01415038

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01415038

Key words

Search

Navigation