Abstract
The kinetics of isothermal and nonisothermal crystallization of polyamide-6 (PA6) containing titania was studied by means of DSC. It was found thatTiO 2 causes an acceleration in the crystallization of polyamide-6 and lowers the value of the Avrami exponent,n. The presence of TiO2 does not affect equilibrium melting pointT 0m , glass temperatureT g, or surface free energiesσ e andσ of the basal and lateral surfaces.
Similar content being viewed by others
References
Rybnikar, F., Collect. Czech. Chem. Commun.27, 106 (1962).
Turska, E., S. Gogolewski, Polymer12, 616 (1971).
Gurato, G., D. Gaidano, R. Zannotti, Makromol. Chem.179, 231 (1978).
De Canolia, F., A. Taglialatela, V. Vittoria, Kolloid-Z. u. Z. Polymere251, 61 (1973).
Wunderlich, B., Macromolecular Physics, vol. II, Academic Press, New York (1976).
Inoue, M., J. Polym. Sci.A1, 2013 (1963).
Beck, H. N., H. D. Ledbetter, J. Appl. Polymer Sci.9, 2131 (1965).
Johanson, U., G. Spilgies, Kolloid-Z. u. Z. Polymere250, 1174 (1972).
Chatterjee, A. M., F. P. Price, J. Polymer Sci. Polymer Physics Edition13, 2369, 2385, 2391 (1975).
Mandelkern, L., Crystallization of Polymers, McGraw-Hill, New York (1964).
Ishibashi, M., Kobunshi Kagaku26, 199 (1969).
Magill, J. H., Polymer6, 367 (1965).
Privalko, V. P., Macromolecules12, 122 (1979).
Ozawa, T., Polymer12, 150 (1971).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Włochowicz, A., Eder, M. The effect of TiO2 on the kinetics of polyamide 6 crystallization. Colloid & Polymer Sci 261, 621–625 (1983). https://doi.org/10.1007/BF01415030
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01415030