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Photochemically induced phase transitions in the system cetyltrimethyl-ammonium bromide-water containing N-methyl-N,N-diphenylamine

  • Colloid Science
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Abstract

Phase transition temperatures from lyotropic liquid crystals to the isotropic micellar solution of the system cetyltrimethylammonium bromide-water (CTAB-H2O) were measured in the presence of 0.1-0.9 weight % of N-methyl-N,N-diphenylamine (MPA). They were determined by optical and viscometric methods and were found to increase as a function of MPA concentration in solutions containing 21 and 23 weight % of CTAB. This effect was reversed when MPA was in situ photochemically converted to N-methylcarbazole, allowing photochemically induced phase transitions.

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Wolff, T. Photochemically induced phase transitions in the system cetyltrimethyl-ammonium bromide-water containing N-methyl-N,N-diphenylamine. Colloid & Polymer Sci 267, 345–348 (1989). https://doi.org/10.1007/BF01413628

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  • DOI: https://doi.org/10.1007/BF01413628

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