Abstract
This paper is concerned with the temperature dependence of mechanical properties of ultradrawn polyethylene in terms of storage modulus E' and loss factor tanδ by the measurement of the complex dynamic tensile modulus over ranges of temperature from 20 to 140 ‡C. Interestingly, E' of a specimen with drawn ratio of 300 is about 120 GPa at 140 ‡C, when the measurement is carried out at a frequency of 100 Hz. This is a very high value. In addition, the drawn specimens were irradiated to try to produce ultra-drawn polyethylene films with more excellent mechanical and thermal properties. However, the melting peak shifts to a lower temperature with increasing radiation dose. This result is probably attributed to the considerably radiation-induced scission of extended chains constructing crystals.
Similar content being viewed by others
References
McHugh AJ, Schulz JM (1973) Kolloid Z u Z Polymere 251:193
Pennings AJ, van der Mark JMMA, Booij JC (1970) Kolloid Z u Z Polymere 236:99
Zwijnenburg A, Pennings AJ (1976) Coll Polym Sci 254:868
Smook J, Torfs JC, van Hutlten PF, Pennings AJ (1980) Polym Bull 2:293
Barham PJ, Keller A (1980) J Mater Sci 15:2229
Zwijnenburg A, Pennings AJ (1975) Coll Polym Sci 253:452
Capaccio G, Ward IM (1974) J Macromol Sci-Phys B19(1):35
Owen AJ, Ward IM (1981) J Macromol Sci-Phys, B19(1):35
Clements J, Capaccio G, Ward IM (1979) J Polym Sci, Polym Phys Ed, 17:693
Kojima S, Desper CR, Porter RS (1978) J Polym Sci, Polym Phys Ed, 16:1721
Smith P, Lemstra PJ, Kalb B, Pennings AJ (1979) Polymer Bulletin 1:733
Smith P, Lemstra PJ (1980) J Mater Sci 15:505
Smith P, Lemstra PJ, Booij HC (1981) J Polym Sci, Polym Phys Ed 19:877
Smith P, Lemstra PJ, Pijppers JPL, Kiel AM (1981) Coll Polym Sci 258:1070
Matsuo M, Manley RStJ (1982) Macromolecules 15:985
Matsuo M, Manley RStJ (1983) Macromolecules 16:1500
Matsuo M, Inoue K, Abumiya N, Manley RStJ, Macromolecules submitted, Matsuo M, Inoue K, Abumiya N (1984) Seni-Gakkaishi 40:275, Matsuo M, Nihon Reoroji Gakkaishi, in press
Flory PJ, Vrij AJ (1963) J Am Chem Soc 85:3548
Blackadder DA, Keniry JS (1971) Macromol Chem 141:211
Bhateja SK, Andrews EH, Young RJ (1983) J Polym Sci, Phys Ed 21:523
Bunn CW (1939) Trans Faraday Soc 35:482
Nakayasu H, Markovitz H, Plazek DJ (1961) Trans Soc Rheol 5:261; Takayanagi, Matsuo T (1967) J Macromol Sci — Phys B1:407; Theα 1 mechanism was associated with grain-boundary phenomena arising from deformation and/or rotation of elastic crystal grain within a viscoelastic amorphous medium. Theα 2 mechanism was associated with a crystal disordering transition due to onset of the torsional and/or translational oscilation of polymer chains within the crystal lattice.
Imada K, Yamamoto T, Shigematsu K, Takayanagi M (1971) J Mater Sci 6:537
de Boer J, Pennings AJ (1981) Polym Bull 5:317
de Boer J, Pennings AJ (1982) Polym Bull 7:309
de Boer J, van den Berg H-J, Pennings AJ (1984) Polym 25:513
Sakurada I, Kaji K (1970) J Polym Sci Part C 31:57
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sawatari, C., Matsuo, M. Dynamic mechanical behavior of ultradrawn polyethylene films produced by gelation/crystallization from solution. Colloid & Polymer Sci 263, 783–790 (1985). https://doi.org/10.1007/BF01412954
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01412954