Abstract
The formation and rheological properties of water-in-water suspensions formed by mixing a dilute nonaqueous solution containing a lightly sulfonated ionomer with an aqueous solution are described. The spheres formed via this process are composed of a very thin (approximately 2000 Å), ionically crosslinked gel membrane which separates the continuous aqueous phase from the encapsulated aqueous phase. The membrane itself is composed of the lightly sulfonated ionomer (i. e., sulfonated polystyrene) swollen with the nonaqueous solvent. Interestingly, surface tension measurements indicate that the sulfonated ionomer in this nonaqueous solvent has no significant interfacial activity. Viscometric measurements confirm that aqueous solvents containing these spheres have considerably enhanced viscosity even in the presence of high concentrations of a salt or acid. Thixotropic behavior is observed at low shear rates, whereas Newtonian behavior is observed at higher rates of shear (> 40 sec−1). Cessation of stress reverts the viscosity to its initial value. Dilution studies show that the streamlines in the flowing exterior aqueous phase cause circulation of the aqueous fluid within the sphere. These results point to the fluid-like characteristics of the gel membrane, since transmission of the stress across the membrane is not dramatically inhibited. Comparison of the low shear rate data with the Mooney equation support these conclusion.
Similar content being viewed by others
References
MacKnight WJ, EarnestJr TR (1981) J Polymer Sci, Macromolecular Reviews 16:41
Eisenberg A, King M (1977) Ion Containing Polymers, Physical Properties and Structure, Academic Press, New York
Bazuin CG, Eisenberg A (1981) Ind Eng Chem Prod Res Dev 20:(2), 271
Eisenberg A (1976) Pure and Appl Chem 46:171
Peiffer DG, Weiss RA, Lundberg RD (1982) J Polymer Sci, Polymer Phys Ed 20:1503
Peiffer DG, Lundberg RD (1983) Polymer 24:300
Lundberg RD, Makowski HS (1980) J Polymer Sci, Polymer Phys Ed 18:1821
Makowski HS, Lundberg RD (1980) Adv Chem Ser, 187:37
Siadat B, Lundberg RD, Lenz RW (1981) Macromolecules 14:773
Lundberg RD, O'Brien DE, Makowski HS, Klein RR (1982) U S Patent No 4,322,329, to Exxon Research and Engineering Company, March 30
Lundberg RD, Makowski HS, O'Brien DE, Klein RR (1982) U S Patent No 4,313,862 to Exxon Research and Engineering Company, February 2
Holliday L (1975) (ed) Ionic Polymers, Applied Sci, London
Longworth R (1978) Plastics and Rubber, Materials and Applications 75
Makowski HS, Lundberg RD, Singhal GS (1975) U S Patent No 3,800,841 to Exxon Research and Engineering Company
Eisenberg A (1974) J Polymer Sci C45:99
Graessley W (1967) J Chem Phys 47:(6)1942
Fujita H, Maekawa E (1962) J Phys Chem 66:1053
Graessley W, Masuda T, Roovers JEL, Hadjichristidis N (1976) Macromolecules 9:127
Brockmeier NF, Westphal SP (1974) Polym Eng Sci 14:782
Utracki LA (1974) Polym Eng Sci 14:308
Cross MM (1965) J Colloid Sci 20:417
Molau GE (1965) J Polymer Sci A3:1267
Molau GE (1965) J Polymer Sci A3:4235
Ossenbach-Sauter M, Riess G (1976) C R Acad Sci, Paris 283:269
Périard J, Banderet A, Riess G (1970) Polymer Letters 8:109
Jeffery GB (1922) Proc Royal Soc A102:161
Rumscheidt FD, Masson SG (1961) J Colloid Sci 16:238
Taylor GI (1934) Proc Royal Soc A146:501
Suzuki K, Watanabe T, Ono S (1970) (ed) Onogi S, Proceedings of the 5th International Congress of Rheology, Volume 2, University of Tokyo Press, Tokyo 339
Scheraga HA (1955) J Chem Phys 23:(8), 1526
Meister JJ (1981) J Rheology 25:(5), 487
Mooney M (1951) J Colloid Sci 6:162
Taylor GI (1932) Proc Royal Soc A138:41
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Peiffer, D.G., Lundberg, R.D. Rheology of water-in-water suspensions formed with lightly sulfonated ionomers. Colloid & Polymer Sci 263, 173–180 (1985). https://doi.org/10.1007/BF01412793
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF01412793