Skip to main content
SpringerLink
Log in

Sulfur isotope effect on95Mo nuclear magnetic shielding in MoS 2−4

  • Published:
Zeitschrift für Physik A Atoms and Nuclei

Abstract

By Fourier transform high resolution NMR spectroscopy the95Mo resonance lines of the tetrathiomolybdate species Mo32S 2−4 and Mo32S3 34S2− have been resolved in aqueous solutions of potassium- and ammonium tetrathiomolybdate. An isotope effect on the Larmor frequency of (0.09±0.01) ppm to lower frequency was found for the substitution of a32S atom by a34S atom in the MoS 2−4 ion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kautt, W.D., Krüger, H., Lutz, O., Maier, H., Nolle, A.: Z. Naturforsch.31a, 351 (1976)

    Google Scholar 

  2. Lutz, O., Nolle, A., Kroneck, P.: Z. Naturforsch.31a, 454 (1976)

    Google Scholar 

  3. Nolle, A.: Z. Physik280A, 231 (1977)

    Google Scholar 

  4. Lutz, O., Nolle, A., Kroneck, P.: Z. Naturforsch. (in press)

  5. Buckler, K.U., Haase, A.R., Lutz, O., Müller, M., Nolle, A.: Z. Naturforsch.32a, 126 (1977)

    Google Scholar 

  6. Gillespie, R.J., Quail, J.W.: J. Chem. Phys.39, 2555 (1963)

    Google Scholar 

  7. Rodmar, S., Rodmar, B., Sharma, M.K., Gronowitz, S., Christiansen, H., Rosen, U.: Acta Chem. Scand.22, 907 (1968)

    Google Scholar 

  8. Linde, S.Aa., Jakobsen, H.J.: J. Magn. Res.17, 411 (1975)

    Google Scholar 

  9. Krüss, G.: Justus Liebigs Ann. Chem.225, 6 (1884)

    Google Scholar 

  10. Lauterbur, P.C.: J. Chem. Phys.42, 799 (1965)

    Google Scholar 

  11. Tiers, G.V.D.: J. Inorg. Nucl. Chem.16, 363 (1961)

    Google Scholar 

  12. Birchall, T., Crossley, S.L., Gillespie, R.J.: J. Chem. Phys.41, 2760 (1964)

    Google Scholar 

  13. Haase, A.R., Lutz, O., Müller, M., Nolle, A.: Z. Naturforsch.31a, 1427 (1976)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Physikalisches Institut, Universität Tübingen, Deutschland

    O. Lutz & A. Nolle

  2. Fachbereich Biologie, Universität Konstanz, Deutschland

    P. Kroneck

Authors
  1. O. Lutz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Nolle
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Kroneck
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

We are indebted to Prof. Dr. H. Krüger for his continuous support of this work. We thank the Deutsche Forschungsgemeinschaft for financial support.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lutz, O., Nolle, A. & Kroneck, P. Sulfur isotope effect on95Mo nuclear magnetic shielding in MoS 2−4 . Z Physik A 282, 157–158 (1977). https://doi.org/10.1007/BF01408158

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01408158

Keywords

Search

Navigation