Abstract
Oscillator strengths of xenon and krypton for transitions from the ground state to the optically allowed states forming the five resonance series were measured by means of high energy electron spectroscopy (HEEIS). The rather irregular behaviour of these oscillator strengths is analyzed with the aid of the known atomic level energies by means of the energy-dependent quantum defect theory. With the parameters obtained by the analysis of the energy loss measurement autoionized lines shapes and the asymmetry parameter for the photoionizationβ of Kr and Xe were calculated in excellent agreement with experimental data from the literature. The comparison of the parameters and their energy dependence for Kr and Xe gives indication that some properties change rather rapidly from Kr to Xe. The theory enables also to predict missing term levels of Kr.
Similar content being viewed by others
References
Lu, K.T.: Phys. Rev. A4, 579 (1971)
Fano, U.: Phys. Rev. A2, 353 (1970);
Fano, U.: J. Opt. Soc. Amer.65, 979 (1975)
Geiger, J.: Z. Physik A276, 219 (1976). Two typographical errors should be corrected: The first autoionizeds′ line is to be designated by 8s′ andD′ 4 should be read −0.59
Geiger, J.: Proc. ¯N Int. Conf. on VUV Rad. Phys., Hamburg, p. 28, Braunschweig: Pergamon-Vieweg 1974
Saile, V., Gürtler, P., Koch, E.E., Kozevnikov, A., Skibowski, M., Steinmann, W.: Applied Optics15, 2559 (1976) and unpublished work; Saile, V. Thesis, Universität München (1976). The author expresses his appreciation to Dr. E.E. Koch for allowing the use of the data before publication
Schmoranzer, H.: Electron Microscopy 1968, Tipographia Poliglotta, Vaticana, Roma (1968), Vol. 1, p. 333
Geiger, J., Schmoranzer, H.: J. Mol. Spectroscopy32, 39 (1969)
Nicolai, R.: Z. Physik228, 16 (1969)
Boersch, H., Geiger, J., Schröder, B.: Abh. Deutsche Akad. Wiss. Berlin, Klasse für Math., Phys., Techn.1967, Nr. 1, p. 15
Bethe, H.: Ann. Phys.5, 325 (1930);
Fano, U.: Phys. Rev.103, 1202 (1956)
Geiger, J.: Z. Physik177, 138 (1964)
Geiger, J.: Thesis, Fakultät für Allg. Ing. Wiss., Techn. Univ., Berlin (1962)
Lu, K.T., Fano, U.: Phys. Rev. A2, 81 (1970)
Seaton, M.J.: Proc. Phys. Soc, London88, 801 (1966)
Starace, A.F.: J. Phys. B: Atom. Molec. Phys.6, 76 (1973)
Lee, C.M., Lu, K.T.: Phys. Rev. A8, 1241 (1973)
Lee, C.M.: Phys. Rev. A10, 584 (1974)
Moore, C.E.: Atomic Energy Levels, NBS Circular No. 467, Vol. III (1958)
Delâge, A., Carette, J.D.: Phys. Rev. A14, 1345 (1976)
Huffman, R.E., Tanaka, Y., Larrabee, J.C.: J. Chem. Phys.39, 902 (1963)
Sommerfeld, A.: Atombau und Spektrallinien (1923), p. 448
Sugiura, Y.: J. Phys. et le Radium8, 113 (1927)
Comes, F.J., Sälzer, H.G., Schumpe, G.: Z. Naturforschung23a, 137 (1968)
Cooper, J., Zare, R.N., in: Lectures in Theoretical Physics, Vol. XI, p. 317 New York: Gordon and Breach 1969
Dill, D.: Phys. Rev. A7, 1976 (1973)
Samson, J.A.R., Gardner, J.L.: Phys. Rev. Letters31, 1327 (1973)
Geiger, J.: Phys. Letters33A, 351 (1970). Note, that in the present report according to the more recent measurement for Kr the oscillator strength ratiof(5s′)/f(5s)=0.89 proved slightly smaller
Huffman, R.E., Tanaka, Y., Larrabee, J.C.: Applied Optics2, 947 (1963)
Metzger, P.H., Cook, G.R.: J. Opt. Soc. America55, 516 (1965)
Carter, V.L., Hudson, R.D.: J. Opt. Soc. America63, 733 (1973)
Stickel, W.: Diplomarbeit Techn. Univ., Berlin 1964
Kim, Y., Desclaux, J.P.: Oscillator Strengths for the Resonance Transitions of Rare Gases, Report ANL-8060 (1973) p. 4
Fano, U.: Comments At. Molec. Phys.2, 30 (1970)
Samson, J.A.R., Cairns, R.B.: Phys. Rev. A8, 1241 (1973)
Author information
Authors and Affiliations
Additional information
Thanks are due to Prof. H. Ehrhardt and his group for an extended use of their computer. Several discussions with Prof. H. Krüger concerning the theoretical background of this paper are also greatfully acknowledged.
Rights and permissions
About this article
Cite this article
Geiger, J. Energy loss spectra of xenon and krypton and their analysis by energy-dependent multichannel quantum defect theory. Z Physik A 282, 129–141 (1977). https://doi.org/10.1007/BF01408155
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01408155