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Studies on the application of salts of complex cations to the microscopic detection of anions

VIII. 1,2-Chloroaquotetramminocobaltic Chloride

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Summary

Characteristic crystalline reaction products were obtained with pyroand orthophosphate ions. In the case of the latter product, the shape of the reaction product seemed to depend on theph of the solution to a great extent.

Zusammenfassung

1,2-Chloroaquotetramminocobaltichlorid [Co(NH3)4(H2O)Cl]Cl2 gibt mit Pyro- und mit Orthophosphat-Ion charakteristische kristalline Reaktionsprodukte. Im Falle des Orthophosphats scheint die Gestalt des Reaktionsproduktes in hohem Maße vomph der Lösung abzuhängen.

Résumé (L)

Le 1,2-chloroaquotetramminocobaltichlorure [Co(NH3)4(H2O)Cl]Cl2 donne avec les ions pyro et ortho phosphoriques des produits de réaction cristallins caractéristiques. La forme du produit de la réaction dans le cas de l'orthophosphate semble dépendre surtout duph de la solution.

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Authors and Affiliations

  1. Analytical Laboratories of Fordham University, New York, N. Y., USA

    L. K. Yanowski & W. A. Hynes

Authors
  1. L. K. Yanowski
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  2. W. A. Hynes
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Additional information

Acknowledgement is made to the Works Progress Administration for the City of New York for assistance rendered under project No. 465-97-3-120, and particularly for the preparation of the reagent substance by Mr.M. Shiller.

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Yanowski, L.K., Hynes, W.A. Studies on the application of salts of complex cations to the microscopic detection of anions. Mikrochim Acta 27, 161–164 (1939). https://doi.org/10.1007/BF01402868

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  • DOI: https://doi.org/10.1007/BF01402868

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