Abstract
In the volume of ZnO single crystals electrons are excited into the conductionband by two-photon absorption of ruby laser light at room temperature. At the edge of the irradiated region there occur a gradient in the concentration and a diffusion of the electrons. As the diffusion is anisotropic in Li-doped ZnO crystals, an axial quadrupole results, which influences measurable charges on the electrodes of the crystal. From the amount of the charge, the product of drift mobility and drift lifetime μDτD can be calculated for Li-doped ZnO. Cu-doped ZnO shows no anisotropic diffusion. By means of photoconductivity experiments, μDτD can be obtained in this case. Finally the coefficients of thedc-effect of ZnO are measured with a Neodymium laser.
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Herrn Prof. Dr. E. Mollwo danke ich für viele fruchtbare Diskussionen und Anregungen, Herrn Dr. R. Heibig für die zur Verfügung gestellten ZnO-Einkristalle und Herrn Dr. W. Kaule für die Möglichkeit, mit dem von ihm gebauten Nd-Laser zu messen. Die Arbeit wurde durch Leihgaben der Deutschen Forschungsgemeinschaft unterstützt.
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Klingshirn, C. Zur Diffusion lichtelektrisch angeregter Elektronen und über dendc-Effekt an ZnO-Kristallen. Z. Physik 248, 433–445 (1971). https://doi.org/10.1007/BF01395693
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DOI: https://doi.org/10.1007/BF01395693