Summary
Halo-compounds of which the half-wave reduction potential is equal to or less negative than that of carbon tetrachloride, are reduced by tetrachloroferrate(II) anions. The bimolecular rate constants measured at 250 in isopropanol are 2 × 10−5 M−1 s−1 and 1 × 10−4 M−1 s−1 respectively for CCl4 and CCl3CO2Me.
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References
I. Wilputte-Steinert,J. Mol. Catal., 4, 113 (1978).
M. Asscher and D. Vofsi,J. Chem. Soc. B, 947 (1968).
W. E. Parham and E. E Schweizer,Org. React.,13, 70 (1963).
I. M. Kolthoff and J. J. Lingane,Polarography, Interscience 1952,vol. 2, p. 648.
Ph. J. Elving, I. Rosenthal and C. S. Tang,J. Am. Chem. Soc., 74, 6112 (1952).
Ph. J. Elving and J. T. Leone,J. Am. Chem. Soc., 82, 5076 (1960).
E. S. Levin and Z. I. Fodiman,Zhur. Fiz. Khim., 28, 601 (1954).
Gmelin Handbuch der anorganische Chemie, Band 14, Eisenorganische Verbindungen Teil A,, p. 85.
T. Akiyama, Y. Hoshi, S. Goto and A. Sugimori,Bull. Chem. Soc. Japan, 46, 1851 (1973).
J. C. D. Brand and W. Snedden,Trans. Farad. Soc., 53, 894 (1957).
C. Furlani, E. Cervone, V. Valenti,J. Inorg. Nucl. Chem., 25, 159 (1963).
G. Winter, D. H. Thompson and J. R. Loehe,Inorg. Synth., 14, 103 (1973).
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Wilputte-Steinert, L. Redox reactions between organic halo-compounds and ferrous cations in isopropanol. Transition Met Chem 3, 172–174 (1978). https://doi.org/10.1007/BF01393538
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DOI: https://doi.org/10.1007/BF01393538