Skip to main content
SpringerLink
Log in

Thermodynamics of copper(II) dicarboxylate coordination in aqueous solution

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The association of H+ and Cu2+ with malonate, maleate, succinate and phthalate ions has been investigated both potentiometrically and calorimetrically at 25° and I = 0.1 mol dm−3 (NaClO4).

The structures of the complexes existing in aqueous solution are proposed on the basis of thermodynamic data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. Shimuzo, R. Tsuchiya and E. Kyuno,Bull. Chem. Soc. Japan, 40, 1162 (1967).

    Google Scholar 

  2. F. Charbonnier,Thermochim. Acta, 10, 269 (1974).

    Google Scholar 

  3. H. Yokobayashi, K. Nagase and K. Muraishi,Bull. Chem. Soc. Japan, 48, 2789 (1975).

    Google Scholar 

  4. K. F. Hyde, P. L. Bocko, M. Lynch, R. Adams and G. Kokoszka,Inorg. Chim. Acta, 19, 51 (1976).

    Google Scholar 

  5. R. P. Bonomo, S. Musumeci, E. Rizzarelli and S. Sammartano,Inorg. Chim. Acta, 14, 251 (1975).

    Google Scholar 

  6. R. P. Bonomo, S. Musumeci, E. Rizzarelli and S. Sammartano,Talanta, 23, 253 (1976).

    Google Scholar 

  7. R. Maggiore, S. Musumeci, E. Rizzarelli and S. Sammartano,Inorg. Chim. Acta, 18, 155 (1976).

    Google Scholar 

  8. R. P. Bonomo, S. Musumeci, E. Rizzarelli and S. Sammartano,J. Inorg. Nucl. Chem., 38, 1851 (1976).

    Google Scholar 

  9. G. H. Nancollas,Coord. Chem. Rev., 5, 379 (1970).

    Google Scholar 

  10. J. J. Christensen, D. J. Eatough and R. M. Izatt,Handbook of Metal Ligand Heats and Related Thermodynamic Quantities, Marcell Dekker, New York, 1975.

    Google Scholar 

  11. G. Ostacoli, P. G. Daniele and A. Vanni,Ann. Chim. Italy, 63, 815 (1973).

    Google Scholar 

  12. C. M. Ke, P. C. Kong, M. S. Cheng and N. C. Li,J. Inorg. Nucl. Chem., 30, 961 (1968).

    Google Scholar 

  13. G. Ostacoli, A. Vanni and E. Roletto,Ric. Sci., 38, 318 (1968).

    Google Scholar 

  14. R. Ghrosh and V. S. H. Nair,J. Inorg. Nucl. Chem., 32, 3033 (1970).

    Google Scholar 

  15. M. Yasada, K. Yamasaki and K. Ohtaki,Bull. Chem. Soc. Japan, 33, 1067 (1960).

    Google Scholar 

  16. V. T. Athavole, N. Mahadevan, P. K. Mathur and R. M. Sathe,J. Inorg. Nucl. Chem., 29, 1947 (1967).

    Google Scholar 

  17. V. S. K Nair,J. Chem. Soc., 1450 (1965).

  18. G. H. Nancollas,Interactions in Electrolyte Solutions, Elsevier, New York, 1966.

    Google Scholar 

  19. R. Griesser and H. Sigel,Inorg. Chem., 9, 1239 (1970).

    Google Scholar 

  20. P. H. Tedesco and J. A. Gonzales Quintana,J. Inorg. Nucl. Chem., 37, 1798 (1975).

    Google Scholar 

  21. E. Campi,Ann. Chim. Italy, 53, 96 (1963).

    Google Scholar 

  22. G. D. Pinching and R. G. Bates,J. Res. Nat. Bur. Standards, 45, 322, 444 (1950).

    Google Scholar 

  23. J. M. Peacock and J. C. James,J. Chem. Soc., 2233 (1951).

  24. A. McAuley, G. H. Nancollas and K. Torrance,Inorg. Chem., 6, 136 (1967).

    Google Scholar 

  25. E. G. Sase and D. V. Jahagirdar,J. Inorg. Nucl. Chem., 37, 985 (1975).

    Google Scholar 

  26. P. G. Daniele, G. Ostacoli and A. Vanni,Atti Accad. Sci. Torino, 109, 547 (1974–1975).

    Google Scholar 

  27. D. P. Graddon,J. Inorg. Nucl. Chem., 5, 219 (1958).

    Google Scholar 

  28. P. Lumme and E. Kari,Acta Chem. Scand., 29, 117, 125 (1975).

    Google Scholar 

  29. N. G. Topp and C. W. Davies,J. Chem. Soc., 87 (1940).

  30. H. J. De Bruin, D. Kaitis and R. B. Temple,Austr. J. Chem., 15, 457 (1962).

    Google Scholar 

  31. T. Nazaki, T. Mise and K. Higaki,Nippon Kagaku Zasshi, 88, 1168 (1967).

    Google Scholar 

  32. T. Tomita, E. Kyuno and R. Tsuchiya,Bull. Chem Soc. Japan, 41, 1130 (1968).

    Google Scholar 

  33. C. Dalgren jr. and F. A. Long,J. Am. Chem. Soc., 82, 1303 (1960).

    Google Scholar 

  34. I. Dellien and L. Malmsten,Acta Chem. Scand., 27, 2877 (1973).

    Google Scholar 

  35. C. W. Davies,J. Chem. Soc., 2093 (1938).

  36. C. W. Davies,Ion Association, Butterworth, London, 1962.

    Google Scholar 

  37. L. G. Sillen and A. E. Martell,Stability Constants of Metal-Ion Complexes, Chem. Soc. Spec. Publ., London, No. 17, 1964; No. 25, 1971.

  38. J. J. Christensen, R. M. Izatt and L. D. Hansen,J. Am. Chem. Soc., 89, 213 (1967) and refs. therein.

    Google Scholar 

  39. R. A. Robinson and R. M. Stokes,Electrolyte Solutions, Academic Press, New York, 1959.

    Google Scholar 

  40. H. K. J. Powell and N, F. Curtis,J. Chem. Soc., 1205 (1966).

  41. J. A. Goedkoop and C. H. MacGillavry,Acta Crystallogr., 10, 125 (1957).

    Google Scholar 

  42. M. Shahat,Acta Crystallogr., 5, 763 (1952).

    Google Scholar 

  43. J. D. Morrison and J. M. Robertson,J. Chem. Soc., 980 (1949).

  44. W. Nowacki and H. Jaggi,Z. Krist., 109, 272 (1957).

    Google Scholar 

  45. S. F. Darlow and W. Cochran,Acta Crystallogr., 14, 1250 (1961).

    Google Scholar 

  46. Y. Okaya and R. Pepinsky,Acta Crystallogr., 10, 324 (1957).

    Google Scholar 

  47. Y. Okaya,Acta Crystallogr., 19, 879 (1965).

    Google Scholar 

  48. R. A. Smith,Acta Crystallogr., B31, 1773 (1975).

    Google Scholar 

  49. M. Biagini Cingi, C. Guastini, A. Musatti and M. Nardelli,Acta Crystallogr., 825, 1833 (1969).

    Google Scholar 

  50. S. F. Darlow,Acta Crystallogr., 14, 1257 (1961).

    Google Scholar 

  51. R. E. Dodd, R. E. Miller and W. F. K. Wynne-Jones,J. Chem. Soc., 2790 (1961).

  52. C. Pigenet, G. Lucazeau and A. Novak,J. Chim. Phys., 73, 141 (1976).

    Google Scholar 

  53. J. Maillals, L. Bardet and L. Maury,J. Mol. Struct., 30, 57 (1976).

    Google Scholar 

  54. L. Eberson and I. Wadso,Acta Chem. Scand., 17, 1552 (1963).

    Google Scholar 

  55. G. Arena, R. Calì, E. Rizzarelli, S. Sammartano, R. Barbucci and M. J. M. Campbell,J. Chem. Soc. Dalton Trans., 581 (1977).

  56. Y. V. Vablokov, V. V. Zelentsov, E. N. Romanenko and V. M. Allenov,Dokl. Akad. Nauk SSSR, 173, 1136 (1967).

    Google Scholar 

  57. H. A. Flaschka,EDTA Titrations, Pergamon, London, 1959.

    Google Scholar 

  58. F. Holmes and D. R. Williams,J. Chem. Soc., 1256 (1967).

  59. G. Arena, R. Calì, E. Rizzarelli and S. Sammartano,Thermochim. Acta, 16, 315 (1976).

    Google Scholar 

  60. G. Arena, C. Rigano, E. Rizzarelli and S. Sammartano,La Chimica e L'Industria, 58, 581 (1976).

    Google Scholar 

  61. C. Rigano, E. Rizzarelli and S. Sammartano, unpublished data.

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Generale, Università di Catania, viale A. Doria 8, 95125, Catania, Italy

    Giuseppe Arena, Rosario Calì, Enrico Rizzarelli & Silvio Sammartano

Authors
  1. Giuseppe Arena
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rosario Calì
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Enrico Rizzarelli
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Silvio Sammartano
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arena, G., Calì, R., Rizzarelli, E. et al. Thermodynamics of copper(II) dicarboxylate coordination in aqueous solution. Transition Met Chem 3, 147–152 (1978). https://doi.org/10.1007/BF01393532

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01393532

Keywords

Search

Navigation