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Synthesis and properties of some chromium(III) β-diketonate complexes

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Summary

Equimolar quantities of CrCl3 · 3THF andβ-diketones, β-dkH, react to yield CrCl2(β-dk) · 2THF and CrCl2(β-dk) · THF complexes in coordinating and noncoordinating solvents respectively. For 1 : 2 and 1 : 3 molar ratios of reactants, derivatives of general formulae CrCl(β-dk)2 and Cr(β-dk)3 (whereβ-dkH = acerylacetrrnc, benzoylacetonc and dibenzoylmethane) have been isolated. All complexes have been characterized by elemental analysis, molecular weights and by i.r. spectra.

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Authors and Affiliations

  1. Department of Chemistry, University of Delhi, 110007, Delhi, India

    Kadidal N. Mahendra, Gyanendra K. Parashar & Ram C. Mehrotra

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  1. Kadidal N. Mahendra
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  2. Gyanendra K. Parashar
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  3. Ram C. Mehrotra
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Mahendra, K.N., Parashar, G.K. & Mehrotra, R.C. Synthesis and properties of some chromium(III) β-diketonate complexes. Transition Met Chem 3, 130–133 (1978). https://doi.org/10.1007/BF01393527

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  • DOI: https://doi.org/10.1007/BF01393527

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