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Copper(I) complexes of rhodanine

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Summary

Some new crystalline copper(I) complexes of rhodanine (HL) have been prepared and studied by i.r. and conductometric methods. The neutral ligand is bonded to the metal atom through the thiocarbonylic sulphur atom. The Cu(HL)2OH · 0.5 H2O complex has a dimeric tetrahedral hydroxyl-bridged structure as have the isostructural halides Cu(HL)2X (X = Cl, Br and I) for which the halide-bridged stretching bands have been identified. The Cu(HL)3A (A = ClO4, BF4, 0.5 SO4 and CF3CO2) complexes have monomeric distorted tetrahedral structures with the anion bonded to the metal.

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References

  1. F. G. Moers and J. J. Steggerda,J. Inorg. Nucl. Chem., 30, 3217 (1968).

    Google Scholar 

  2. W. J. Geary,Coord. Chem. Rev., 7, 81 (1971).

    Google Scholar 

  3. A. C. Fabretti and G. Peyronel,Transition Met. Chem., 2, 224 (1977).

    Google Scholar 

  4. G. C. Pellacani, G. Peyronel, T. Feltri and L. Menabue,Spectrochim. Acta, 32A, 285 (1976).

    Google Scholar 

  5. A. Pignedoli and G. Peyronel,Spectrochim. Acta, 32A, 1739 (1976).

    Google Scholar 

  6. R. Bartistuzzi, G. Peyronel and G. Debbi,Z. Anorg. Allg. Chem., 427, 274 (1976).

    Google Scholar 

  7. K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1970, p. 167.

    Google Scholar 

  8. G. L. Bottger and A. L. Geddes,Spectrochim. Acta, 23A, 1551 (1967).

    Google Scholar 

  9. J. R. Ferraro,Low-Frequency Vibrations of lirorganic and Coordination Compounds, Plenum Press, New York, 1971, pp. 175, 179, 75.

    Google Scholar 

  10. B. K. Teo and D. M. Barnes,Inorg. Nucl. Chem. Lett. 12, 681 (1976).

    Google Scholar 

  11. W. R. McWhinnie and V. Rattanaphani,Inorg. Chim. Acta, 9, 153 (1974).

    Google Scholar 

  12. L. Volponi, B. Zarli and G. G. De Paoli,Inorg. Nucl. Chem. Lett., 8, 309 (1972).

    Google Scholar 

  13. M. J. Campbell, R. Grzeskowiak and M. Goldstein,Spectrochim. Acta, 24A, 1149 (1968).

    Google Scholar 

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Authors and Affiliations

  1. Istituto di Chimica Generale e Inorganica, University of Modena, 41100, Modena, Italy

    Antonio C. Fabretti, Giorgio Peyronel & Gian Carlo Franchini

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  1. Antonio C. Fabretti
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  2. Giorgio Peyronel
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  3. Gian Carlo Franchini
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Fabretti, A.C., Peyronel, G. & Franchini, G.C. Copper(I) complexes of rhodanine. Transition Met Chem 3, 125–127 (1978). https://doi.org/10.1007/BF01393525

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