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Titanium(IV) and zirconium(IV) derivatives of tetradentate schiff bases

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Summary

Titanium and zirconium isopropoxides react with the tetradentate Schiff bases, I)is-salicylaldehyde-o-phenylenediimine (SBH2 ) and bis-salicylaldehyde-p-phenylencdiimine (S′B′H2) in anhydrous benzene in 1: 1 and 1 :2 molar ratios to give almost quantitative yields of M(OPr-i)2 (SB) and M(OPr-i)2(SB)(SBH), where M = Ti or Zr and [SB]2 is the anion of the corresponding Schiff base, SBH2. The i.r. spectra of the completes have been recorded and tentative assignments for C=N and C-O stretching frequencies made.

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Authors and Affiliations

  1. Department of Chemistry, University of Jodhpur, 342001, Jodhpur, India

    J. Uttamchandani & R. N. Kapoor

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  1. J. Uttamchandani
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  2. R. N. Kapoor
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Uttamchandani, J., Kapoor, R.N. Titanium(IV) and zirconium(IV) derivatives of tetradentate schiff bases. Transition Met Chem 3, 79–81 (1978). https://doi.org/10.1007/BF01393514

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