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Amine adducts and piperidinido compounds of iron(III)

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Summary

Piperidine reacts with the FeCI(o-H2NC6H4CO2)2 · H2O, (1) and FeCl(o-HOC6H4CO2)2 · H2O, (2), to give the piperidinido-N complexes, Fe(NC5H10)(o-H2NC6H4CO2)2 and Fe(NC5H10)(o-OC6H4CO2), respectively. n-Butylamine and pyridine, combine with (1) and (2) either by removal of water or by formation of simple addition compounds or chelate rings. The i.r. spectra, molar conductances, magnetic moments, molecular weights and thermal decompositions of some of these products have been studied.

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References

  1. R. C. Paul, R. C. Narula, S. Kaur and S. K. Vasisht,Transition Met. Chem., 1, 284 (1976).

    Google Scholar 

  2. R. C. Paul, R. C. Narula and S. K. Vasisht,Transition Met. Chem., 2, 69 (1977).

    Google Scholar 

  3. R. C. Paul, R. C. Narula and S. K. Vasisht,Transition Met. Chem., 2, 152 (1977).

    Google Scholar 

  4. D. C. Bradley and M. H. Gitlitz,J. Chem. Soc. A, 980 (1969).

  5. D. Nicholls in J. C. Bailar, H. J. Emeleus, R. Nyholm and A. F. Trotman-Dickenson, Eds.,Comprehensive Inorganic Chemistry, Pergamon, New York, 1973, p. 3.

    Google Scholar 

  6. A. Cabana and C. Sandorfy,Can. J. Chem., 40, 615 (1962).

    Google Scholar 

  7. N. N. Greenwood and K. Wade,J. Chem. Soc., 1130 (1960).

  8. N. S. Gill, R. H. Nuttal, D. B. Saife and D. W. A. Sharp,J. Inorg. Nucl. Chem., 18, 79 (1961).

    Google Scholar 

  9. N. A. Ali, S. B. Livingstone and D. J. Phillips,Inorg. Chins. Acta, 7, 179 (1973).

    Google Scholar 

  10. N. W. Allcock, V. M. Tracy and T. C. Waddington,J. Chem. .Soc. Dalton Trans., 2243 (1976).

  11. G. J. Long, W. T. Robinson, W. P. Tappmeyer and D. L. Bridges,J. Chem. Soc. Dalton Trans., 573 (1973).

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Paul, R.C., Narula, R.C. & Vasisht, S.K. Amine adducts and piperidinido compounds of iron(III). Transition Met Chem 3, 76–79 (1978). https://doi.org/10.1007/BF01393513

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  • DOI: https://doi.org/10.1007/BF01393513

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