Abstract
The gas-phase oxidation of 1-hexene on a palladium film has been investigated in a gradient-free reactor at atmospheric pressure and temperatures of 293–693 K, at flow rates of 0.3–0.15 liter/min and an initial concentration of hexene in air of 15.5·10−4 M. Autooscillation phenomena have been observed and a hysteresis effect in the reaction rate as function of temperature, caused by the branched-chain heterogeneous-homogeneous reaction mechanism.
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Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 24, No. 1, pp. 107–110, January–February, 1988.
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Shaprinskaya, T.M. Hysteresis effect and autooscillation phenomena in the oxidation of 1-hexene on palladium. Theor Exp Chem 24, 99–103 (1988). https://doi.org/10.1007/BF01392199
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DOI: https://doi.org/10.1007/BF01392199