Literature cited
Yu. P. Egorov, Structure and Spectroscopic Properties of Organic Compounds with E=N Bond, [in Russian], Nauk. Dumka, Kiev (1987).
R. Hudson, Structure and Mechanism of the Reactions of Organophosphorus Compounds [Russian translation], Mir, Moscow (1967).
H. R. Allcock, “Recent advances in phosphazene (phosphonitrilic) chemistry,” Chem. Rev.,72, No. 4, 315–356 (1972).
E. N. Tsvetkov and A. A. Korkin, “Antiboinding orbitals and their role in electronic interactions in compounds that have a phosphoryl group,” Teor. Eksp. Khim.,21, No. 1, 39–45 (1985).
Yu. P. Egorov and A. A. Kudryavtsev, “Structure,31P chemical shifts and frequencies ϒp=n of some classes of phosphazo compounds,” Zh. Obshch. Khim.,53, No. 10, 2222–2228 (1983).
Yu. P. Egorov, A. A. Kudryavtsev, A. M. Pinchuk, et al., “Structure and91P chemical shifts (δ) of phosphazoalkanes,” Teor. Eksp. Khim.,18, No. 1, 58–65 (1982).
P. C. Murphy and J. Tebby, “24-01-Bonding effects on the91P NMR. Chemical shifts of N-aryl iminophosphoranes.” Phosphorus Chemistry, Proc. Int. Conf., 1981, Am. Chem. Soc., Washington (1981), pp. 573–576.
J. Bodecker, P. Kochrits, H. Koppel and R. Radeglia, “31P NMR Untersuchungen N-aryl-sub-stituierter Iminotriphenylphosphorane: Hammett-bezeihung zwischen31P Verschiebung und Substituiertenkonstanten,” J. Prakt. Chem.,322, No. 5, 735–741 (1980).
E. S. Kozlov, S. N. Gaidamaka, and R. Kh. Sadykov, “Trichloromethyldichlorophosphazoarenes,” Zh. Obshch. Khim.,46, No. 3, 552–555 (1976).
R. Mathis, N. Zenati, N. Aved, and M. Sanchez, “La basicité de l'atome d'azote dans quelques iminophosphanes\(\begin{array}{*{20}c} {} & {} & {} & {} & {} & {} & {} & {} \\ ( & - & P & = & N & - & R & ) \\ {} & {} & {} & {} & {} & {} & {} & {} \\ \end{array} \) et aminophosphanes\(\begin{array}{*{20}c} {} & {} & {} & {} & {} & {} & {} \\ ( & {} & P & - & N & {R_2 } & ) \\ {} & {} & {} & {} & {} & {} & {} \\ \end{array} \). Etude en spectrographie infrarouge,” Spectrochim. Acta. A,38, No. 11, 1181–1184 (1982).
V. A. Shokol, A. A. Kisilenko, and G. I. Derkach, “IR spectra of phosphazo compounds with14N and15N nitrogen isotopes and the31P NMR spectra of phosphazocarbacyls,” Zh. Obshch. Khim.,39, No. 4, 874–879 (1969).
J. Ruppert and R. Appel, “Ein neues Verfahren zur Darstellung von N-Cyaniminophosphoranes,” Chem. Ber.,111, No. 2, 751–758 (1978).
A. P. Marchenko, G. N. Koidan, and A. M. Pinchuk, “Triaminophosphazochlorides,” Zh. Obshch. Khim.,53, No. 3, 670–672 (1983).
B. M. Lynch, “Proportionality relationships in the carbon-13 NMR spectra of para-disubstituted benzenes: a new interpretation of nonadditive behavior,” Can. J. Chem.55, No. 3, 541–547 (1977).
V. A. Palm, Fundamentals of the Quantitative Theory of Organic Reactions [in Russian], Khimiya, Leningrad (1967).
J. H. Letcher and J. R. van Wazer, “Quantum-mechanical theory of31P NMR chemical shifts,” Topics Phosph. Chem.,5, 75–167 (1967).
G. K. Genkina, V. A. Gilyarov, and M. I. Kabachnik, “The electronic effect of XYZP=groups,” Dokl. Akad. Nauk SSSR,188, No. 6, 1288–1292 (1969).
H. H. Jaffe, “Multiple bonds involving d-orbitals,” Inorg. Chem.,13, No. 2, 301–314 (1974).
M. Yu. Antipin, Yu. T. Struchkov, and Yu. P. Egorov, “X-ray structural study of tris-(ethylphenylamido)phosphazohydride (EtPhN)3P=NH and the nature of the phosphorus-nitrogen bond,” Teor. Eksp. Khim.,20, No. 3, 357–361 (1984).
W. F., Reynolds, I. R. Peat, M. H. Freedman, and J. R. Lyerla, “An investigation into the nature of π-inductive effects: Tr-polarization effect in phenylalkanes with polar or charged substituents,” Can. J. Chem.,51, No. 7, 1857–1869 (1973).
Yu. P. Egorov, L. M. Litvinenko, and A. F. Popov, “Spectroscopic study of the conduction of electronic effects by element-nitrogen bridge groups (E = P, S, Se),” Teor. Eksp. Khim.,20, No. 3, 357–361 (1984).
M. Dewar, The Theory of Molecular Orbitals in Organic Chemistry [Russian translation], Mir, Moscow (1972).
H. R. Allcock, P. J. Harris, and M. S. Connolly, “Synthesis of alkylphosphazenes via copper-phosphazene intermediates,” Inorg. Chem.,20, No. 1, 11–16 (1981).
W. Buchner and W. Wolfsberger, “29Si,31P,und13C Kernresonanzuntersuchungen am N-silylierten Triorganophosphiniminen,” Z. Naturforsch.,32, No. 8, 967–974 (1977).
K. A. O. Starzewski and H. tom Dieck, “Electronic structure and reactivity. 8. Iminophosphoranes — simple ylide analogs? An investigation of quantitative and phenomenological differences,” Inorg. Chem.,18, No. 12, 3307–3316 (1979).
A. S. Tarasevich and A. M. Nesterenko, “Calculation of31P NMR chemical shifts in a series of phosphazoalkanes,” Teor. Eksp. Khira.,17, No. 6, 750–756 (1981).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 24, No. 1, pp. 20–28, January–February, 1988.
Rights and permissions
About this article
Cite this article
Egorov, Y.P. Intermolecular interactions of substituents and31P NMR spectra in phosphazo (phosphinimine) compounds. Theor Exp Chem 24, 18–25 (1988). https://doi.org/10.1007/BF01392185
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01392185