Abstract
The possible mechanisms of enhanced superconductivity in PdH(D) systems are discussed. It is concluded that quenching of paramagnons due to reduced coulomb pseudopotentialalone cannot account for the highT c observed in these systems. Possible participation of the high frequency optic phonon band in BCS-type interaction could lead to a highT c and an opposite isotope effect in these systems. The possibility of the occurrence of some high-q soft modes due to large lattice expansion in these systems to yieldT c ∼9 K requires about 2-fold softing of the effective Pd-Pd force constant in PdH compared to that in metallic Pd.
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This research was supported in part by the National Science Foundation under Grant GH-33634.
I am indebted to Professor John Bardeen and Mr. James Bray for numerous discussions. I am thankful to Drs. W. Buckel, B. Eichler and A. Stritzker for sending a preprint of their work before publication.
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Ganguly, B.N. High frequency local modes, superconductivity and anomalous isotope effect in PdH(D) systems. Z. Physik 265, 433–439 (1973). https://doi.org/10.1007/BF01391800
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DOI: https://doi.org/10.1007/BF01391800