Abstract
It is shown by field applied molecular dynamics computer simulation (FMD) of liquid water that the frequency doubled optical Stark effect is accompanied by novel second order rise transients which have no known counterpart in orientational theory, based on Langevin/Kielich functions. In the statistically stationary, post transient, steady state, correlation function have been computed which are intricately dependent on the frequency of the pump laser. These transients can be obtained experimentally by modifications of optical Stark effect apparatus for measurement on a femtosecond time scale.
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Hanna, D.C., Yuratich, M.A., Cotter, D., (eds.): Nonlinear optics of free atoms and molecules. (Springer Series in Optical Sciences, Vol. 17) Berlin, Heidelberg, New York: Springer 1979
Kielich, S.: In: Davies, M. (Senior Reporter): Dielectric and related molecular processes, vol. 1, London: Chemical Society 1972
Kielich, S.: Nonlinear molecular optics. Moscow: Nauka 1981
O'Konski, C.T., Yoshioka, K., Orttung, W.H.: J. Chem. Phys.63, 1558 (1959)
Wagnière, G.: Phys. Rev. A40, 2437 (1989)
Barron, L.D.: Molecular light scattering and optical activity. Cambridge: Cambridge Univ. Press 1982
Woźniak, S., Wagnière, G., Zawodny, R.: Phys. Lett. A (in press)
Woźniak, S., Zawodny, R.: Phys. Lett. A85, 111 (1981)
Evans, M.W.: J. Chem. Phys.76, 5473, 5480 (1982);77, 4632 (1982);78, 925 (1983);79, 5403 (1983)
Evans, M.W., Coffey, W.T., Grigolini, P.: Molecular diffusion, chapters 1 and 2. New York: Wiley Interscience 1984: Moscow: MIR (1988)
Evans, M.W., Grigolini, P., Pastori, G., Prigogine, I., Rice, S.A. (eds.): Advances in chemical physics, vol. 62, chapter 5. New York: Wiley Interscience 1985
Evans, M.W., Lie, G.C., Clementi, E.: J. Chem. Phys.87, 6040 (1987)
Evans, M.W., Lie, G.C., Clementi, E.: Z. Phys. D-Atoms, Molecules and Clusters7, 397 (1988)
Evans, M.W.: In: Prigogine, I., Rice, S.A. (eds.): Advances in chemical physics, vol. 81. New York: Wiley Interscience (in press)
Evans, M.W.: J. Mol. Liq.34, 269 (1987)
Evans, M.W., Swamy, K.N., Refson, K., Lie, G.C., Clementi, E.: Phys. Rev. A36, 3935 (1988)
Evans, M.W., Lie, G.C., Clementi, E.: J. Chem. Phys.88, 5157 (1988)
Evans, M.W., Evans, G.J., Coffey, W.T., Grigolini, P.: Molecular dynamics, chapter 1, New York: Wiley Interscience 1982
Evans, M.W., Woźniak, S., Wagnière, G.H.: Physica B (in press)
Khanarian, G., Kent, L.: J. Chem. Soc. Faraday Trans. 277, 495 (1981)
Zeiss, G.D., Meath, W.J.: Mol. Phys.30, 161 (1975)
Jortner, J., Levine, R.D., Prigogine, I., Rice, S.A. (eds.): Advances in chemical physics, vol. 47. New York: Wiley Interscience 1981
Kalpouzos, C., McMorrow, D., Lotshaw, W.T., Kenney-Wallace, G.A.: Chem. Phys. Lett.150, 138 (1988)
Evans, M.W., Lie, G.C., Clementi, E.: Phys. Lett. A130, 289 (1988)
Evans, M.W., Woźniak, S., Wagnière, G.H.: Physica B (in press)
Pershan, P.S., Ziel, J.P. van der, Malmstrom, L.D.: Phys. Rev. A143, 574 (1966)
Evans, M.W.: Phys. Rev. Lett.64, 2909 (1990)
Evans, M.W.: Phys. Chem.95, 2256 (1991)
Evans, M.W.: Chem. Phys.150, 197 (1991)
Evans, M.W., Woźniak, S., Wagnière, G.H.: Physica B (in press)
Shen, Y.R.: The principles of non-linear optics, New York: Wiley 1984
Gray, H.R., Stroud, C.R.: Opt. Commun.25, 359 (1978)
Molander, W.A., Stroud, C.R. Jr., Yeazell, J.A.: J. Phys. 19, L461 (1986)
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Evans, M.W. Field applied (FMD) computer simulation of the frequency doubled optical Stark effect. Z. Physik B - Condensed Matter 85, 135–143 (1991). https://doi.org/10.1007/BF01387799
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DOI: https://doi.org/10.1007/BF01387799