Abstract
Doping of C60 fullerene with KTl1.5 results in superconductivity withT onset c =17.6 K as shown by a dc magnetization measurement. Preliminary13C NMR studies on a doped and undoped sample are reported. Compared to original C60 the linewidth increases by a factor of 3, the resonance frequency is shifted by 42 ppm, and the relaxation rateT −11 is an order of magnitude larger in the intercalated material at room temperature. Both observations support the picture of a metallic sample.
References
Hannay, N.B., Geballe, T.H., Matthias, B.T., Andres, K., Schmidt, P., MacNair, D.: Phys. Rev. Lett.14, 225 (1965)
Belash, I.T., Bronnikov, A.D., Zharikov, O.V., Palnichenko, A.V.: Synth. Metals36, 283 (1990)
Kroto, H.W., Heath, J.R., O'Brien, S.C., Curl, R.F., Smalley, R.E.: Nature318, 162 (1985)
Hebard, A.F., Rosseinsky, M.J., Haddon, R.C., Murphy, D.W., Glarum, S.H., Palstra, T.T.M., Ramirez, A.P., Kortan, A.R.: Nature350, 600 (1991)
Stephens, P.W., Mihaly, L., Lee, P.L., Whetten, R.L., Huang, S.-H., Kaner, R., Deiderich, F., Holczer, K.: Nature351, 632 (1991)
Rosseinsky, M.J., Ramirez, A.P., Glarum, S.H., Murphy, D.W., Haddon, R.C., Hebard, A.F., Palstra, T.T.M., Kortan, A.R., Zahurak, S.M., Makhija, A.V.: Phys. Rev. Lett.66 2830 (1991)
Holczer, K., Klein, O., Huang, S.-M., Kaner, R.B., Fu, K.-J., Whetten, R.L. Diederich, F.: Science252, 1154 (1991)
Vogel, F.L., Wachnik, R., Pendrys, L.A.: In: Physics of Intercalation Compounds. Pietronero, L., Tosatti, E. (eds.), p. 288. Berlin, Heidelberg, New York: Springer 1981
Wachnik, R.A., Pendrys, L.A., Vogel, F.L., Lagrange, P.: Solid State Commun.43, 5 (1982)
Iye, Y., Tanuma, S.: In: Graphite Intercalation Compounds. Tanuma, S., Kamimura, H., (eds.), p. 253 Summary Report of Special Distinguished Research Project (56122027), Japan 1984
Krätschmer, W., Lamb, D.L., Fostiropoulos, K., Huffman, D.R.: Nature347, 354 (1990)
Yannoni, C.S., Johnson, R.D., Meijer, G., Bethune, D.S., Salem, J.R.: J. Phys. Chem.95, 9 (1991)
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Kraus, M., Freytag, J., Gärtner, S. et al. Superconductivity and NMR investigations of KTl1.5-doped C60 . Z. Physik B - Condensed Matter 85, 1–2 (1991). https://doi.org/10.1007/BF01387780
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DOI: https://doi.org/10.1007/BF01387780