Abstract
Orthorhombic crystals of the title compound, C7H16ClNO2SSn, belong to space groupP212121, witha = 6.658(5),b = 10.974(3),c = 17.144(5) Å, andZ = 4. The diffractometer data, measured with CuKα radiation, has been refined to anR index of 0.053 for 1110 observed terms. The geometry about the Sn atom in the monomeric complex units is distorted trigonal bipyramidal; the N and Cl atoms are in the apical positions, and the Sn lies at 0.107(1) Å from the equatorial plane. The Sn-Cl, Sn-S, and Sn-N bonds have lengths 2.523(4), 2.413(3), and 2.434(12) respectively, and the angle N-Sn is 166.9(3) °.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Aldridge, W. N., and Cremer, J. E. (1955)Biochem. J. 61, 406.
Aldridge, W. N. (1976) inOrganotin Compounds: New Chemistry and Applications. Advances in Chemistry Series, Vol. 157, J. J. Zuckerman, ed. (American Chemical Society, Washington, D.C.), pp. 186–197.
Bancroft, G. M., Davies, B. W., Payne, N. C., and Shan, T. K. (1975)J. Chem. Soc. Dalton Trans., 973.
Busing, W. R. and Levy, H. A. (1957)Acta Cryst. 10, 180.
Buttenshaw, A. J., Duchêne, M., and Webster, M. (1975)J. Chem. Soc. Dalton Trans., 2230.
Cromer, D. T., and Mann, J. B. (1968)Acta Cryst. A 24, 321.
Cromer, D. T., and Liberman, D. (1970)J. Chem. Phys. 53, 1891.
Cunningham, D., Douek, I., Frazer, M. J., Partlin, M., and Mathews, J. D. (1975)J. Organomet. Chem. 90, C23.
Davies, A. G., Milledge, H. J., Purley, D. C., and Smith, P. J. (1970)J. Chem. Soc. (A), 2862.
Domazetis, G., Magee, R. J., and James, B. D. (1978)J. Organomet. Chem. 162, 239.
Domazetis, G., Magee, R. J., and James, B. D. (1979)Inorg. Chim. Acta 32, L48.
Domazetis, G., Mackay, M. F., Magee, R. J., and James, B. D. (1979)Inorg. Chim. Acta 34 L247.
Doyle, P. A., and Turner, P. S. (1968)Acta Cryst. A 24, 390.
Drew, M. G. B., and Kay, A. (1971)J. Chem. Soc. (A), 1846.
Farrow, B. G., and Dawson, A. P. (1978)Eur. J. Biochem. 86, 85.
Forder, R. A., and Sheldrick, G. M. (1970)J. Organomet. Chem. 21, 115.
Freeman, H. C. (1967)Adv. Protein Chem. 22, 257.
Freeman, H. C. (1973) inInorganic Biochemistry, Vol. 1, G. L. Eichorn, ed. (Elsevier, Amsterdam), p. 124.
Furue, K., Kimura, T., Yasuoka, N., Kasai, N., and Kakudo, M. (1970)Bull. Chem. Soc. Jpn. 43, 1661.
Ho, B. Y. K., and Zuckerman, J. J. (1973)J. Organomet. Chem. 49, 1.
Ho, B. Y. K., Zubieta, J. A., and Zuckerman, J. J. (1975)J. Chem. Soc. Chem. Commun., 88.
Huber, F., Haupt, H. J., Preut, H., Barbieri, R., and Lo Giudice, M. T. (1977)Z. Anorg. Allg. Chem. 432, 51.
Huheey, J. E. (1978) inInorganic Chemistry, 2nd edn. (Harper and Row, New York), p. 232.
Hulme, R. (1963)J. Chem. Soc., 1524.
Johnson, C. K. (1965)Fortran Thermal-Ellipsoid Plot Program (Ortep). (Oak Ridge National Laboratory, Oak Ridge, Tennessee).
Koten, G., and Noltes, J. G., (1976)J. Organomet. Chem. 118, 183.
Mezenbach, B., and Bleckmann, P. (1975)J. Organomet. Chem. 91, 291.
Schlemper, E. O. (1967)Inorg. Chem. 6, 2012.
Sheldrick, G. M. (1976)Program for Crystal Structure Determination (Shelx76). (Cambridge Univ., England).
Zahrobsky, R. F. (1971)J. Am. Chem. Soc. 93, 3313.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Domazetis, G., Mackay, M.F. Crystal and molecular structure of chloro(ethyl L-cysteinato-N,S) dimethyltin (IV). Journal of Crystal and Molecular Structure 9, 57–65 (1979). https://doi.org/10.1007/BF01387558
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01387558